683208-97-1

Basic information

• Product Name: Carbamic acid, [(1R)-1-[4-[(diethoxyphosphinyl)methyl]phenyl]-3-butenyl]-, phenyl ester
• CAS NO: 683208-97-1
• Molecular Formula: C22H28NO5P
• Molecular Weight: 417.442
• Mol File: 683208-97-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(1R)-1-[4-[(diethoxyphosphinyl)methyl]phenyl]-3-butenyl]-, phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(1R)-1-[4-[(diethoxyphosphinyl)methyl]phenyl]-3-butenyl]-, phenyl ester(683208-97-1)
• EPA Substance Registry System: Carbamic acid, [(1R)-1-[4-[(diethoxyphosphinyl)methyl]phenyl]-3-butenyl]-, phenyl ester(683208-97-1)

Safety Data

• Hazardous Substances Data: 683208-97-1(Hazardous Substances Data)

Upstream product

• 683209-01-0 [4-((R)-1-Azido-but-3-enyl)-benzyl]-phosphonic acid diethyl ester 
• 683209-00-9 [4-((S)-1-Hydroxy-but-3-enyl)-benzyl]-phosphonic acid diethyl ester 
• 125185-25-3 (4-formylphenyl)methylphosphonic acid diethyl ester 
• 51359-78-5 4-(bromomethyl)benzaldehyde 
• 17201-43-3 4-cyanobenzyl bromide 

Downstream Products

• 683209-04-3 [4-((E)-(10R,15S,19S)-19-Carbamoylmethyl-15-naphthalen-1-ylmethyl-8,18,21-trioxo-7,9,17,20-tetraaza-spiro[5.15]henicos-12-en-10-yl)-benzyl]-phosphonic acid diethyl ester 
• 683209-05-4 [4-((Z)-(10R,15S,19S)-19-Carbamoylmethyl-15-naphthalen-1-ylmethyl-8,18,21-trioxo-7,9,17,20-tetraaza-spiro[5.15]henicos-12-en-10-yl)-benzyl]-phosphonic acid diethyl ester 
• 683209-03-2 {4-[(R)-1-(3-{1-[(S)-2-Carbamoyl-1-((S)-2-naphthalen-1-ylmethyl-pent-4-enylcarbamoyl)-ethylcarbamoyl]-cyclohexyl}-ureido)-but-3-enyl]-benzyl}-phosphonic acid diethyl ester 

Relevant articles and documents

Enantioselective Synthesis of Metathesis-Derived Ureapeptoid Macrocycles

Ring-closing metathesis (RCM) was used for the preparation of the first member of a new class of ureapeptoid-containing macrocycles. Key to the approach was the enantioselective synthesis of functionalized carbamoyl alkenylglycine equivalents using (-)-B-allyldiisopinocampheylborane [(-)-d-Ipc2Ball]-mediated asymmetric allylation.