68407-94-3

Basic information

• Product Name: N-1-Tritylbenzotriazole
• Synonyms: N-1-Tritylbenzotriazole
• CAS NO: 68407-94-3
• Molecular Weight: 361.446
• Mol File: 68407-94-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: N-1-Tritylbenzotriazole(CAS DataBase Reference)
• NIST Chemistry Reference: N-1-Tritylbenzotriazole(68407-94-3)
• EPA Substance Registry System: N-1-Tritylbenzotriazole(68407-94-3)

Safety Data

• Hazardous Substances Data: 68407-94-3(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 519-73-3 triphenylmethane 
• 76-83-5 trityl chloride 
• 87268-78-8 2-trityl-5-phenyl-2H-tetrazole 

Downstream Products

• 132870-27-0 N-2-Tritylbenzotriazole 

Relevant articles and documents

Design, synthesis, and antifungal activity of triazole and benzotriazole derivatives

This study describes the design, synthesis and evaluation of a novel series of 1,2,4-triazole and benzotriazole derivatives as inhibitors of cytochrome P450 14α-demethylase (14DM). The chemical structures of the new compounds were confirmed by elemental a

Nitrosation of derivatives of hydrazines, IX: Novel oxidative C-N-coupling of indazoles and benzotriazoles with cyclohepatriene, di- and triphenylmethane derivatives

In the presence of 2,3-dichloro-5,6-dicyano-benzoquinone (DDQ) indazoles and benzotriazoles react with compounds forming stabilized carbenium ions like cycloheptatriene, di- and triphenylmethane, fluorene, xanthene and thioxanthene, yielding C-N-coupled products.

Studies on the Thermal Isomerization of N-Arylmethylbenzotriazoles

The thermal isomerizations of N-benzyl-, N-diarylmethyl- and N-trityl-benzotriazole, and of N--, and N-trityl-5,6-dimethylbenzotriazole under nitrogen have been investigated.In all these cases , the N-1 isomer predominates over the N-2 isomer at thermodynamic equilibrium, to an extent which depends on the steric bulk of the N-substituent.The rate of attainment of equilibrium depends on the electronic effects of the substituents, both in the benzotriazole ring and in the migrating group.These results, in conjunction with a cross-over experiment, support a mechanism involving a heterolytic N-C bond cleavage followed by an intermolecular rearrangement.