68668-00-8

Basic information

• Product Name: Benzene, 1-methoxy-4-[(2-phenylethenyl)sulfonyl]-, (E)-
• CAS NO: 68668-00-8
• Molecular Formula: C15H14O3S
• Molecular Weight: 274.34
• Mol File: 68668-00-8.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[(2-phenylethenyl)sulfonyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[(2-phenylethenyl)sulfonyl]-, (E)-(68668-00-8)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[(2-phenylethenyl)sulfonyl]-, (E)-(68668-00-8)

Safety Data

• Hazardous Substances Data: 68668-00-8(Hazardous Substances Data)

Upstream product

• 4110-77-4 (E)-β-chlorostyrene 
• 4346-59-2 para-methoxyphenyldiazonium chloride 
• 1950-68-1 4-methoxybenzenesulfonyl hydrazide 
• 637-44-5 phenylpropyolic acid 
• 6462-50-6 sodium 4-methoxybenzenesulfinate 
• 621-82-9 Cinnamic acid 
• 140-10-3 (E)-3-phenylacrylic acid 
• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 
• 100-42-5 styrene 
• 6140-09-6 sodium 4-methoxy-benzenesulfonate 
• 536-74-3 phenylacetylene 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 696-63-9 4-Methoxybenzenethiol 
• 19488-09-6 sodium 4-methoxyphenylthiolate 

Relevant articles and documents

PhB(OH)2-Promoted Electrochemical Sulfuration-Formyloxylation of Styrenes and Selectfluor-Mediated Oxidation-Olefination

We report a PhB(OH)2-promoted electrochemical sulfuration-formyloxylation reaction of styrenes employing commercially available thiophenols/thiols as thiolating agents. Specifically, metal catalysts and external chemical oxidants are not needed in the reaction for the formation of β-formyloxy sulfides, and these sulfides can be further converted to (E)-vinyl sulfones via the Selectfluor-mediated oxidation-olefination. Notably, on the basis of this electrochemical oxidation strategy, β-hydroxy sulfide, β-formyloxy sulfoxide, β-formyloxy sulfone, and (E)-vinyl sulfoxide can also be easily prepared.

Copper-Catalyzed Heck-Type Couplings of Sulfonyl Chlorides with Olefins: Efficient and Rapid Access to Vinyl Sulfones

A copper-catalyzed redox-neutral alkene sulfonylation reaction has been developed. This reported protocol can be easily scale up to a gram scale, and smoothly applied to the late-stage modification of several bioactive molecules.

Electrochemical sulfonylation of alkenes with sulfonyl hydrazides: A metal- And oxidant-free protocol for the synthesis of (: E)-vinyl sulfones in water

An efficient electrochemical transformation of a variety of alkenes and sulfonyl hydrazides into vinyl sulfones with a catalytic amount of tetrabutylammonium iodide in water is reported. The reaction proceeds smoothly to afford vinyl sulfones with good selectivities and yields at room temperature under air in an undivided cell. Cyclic voltammograms and control experiments have been performed to provide preliminary insight into the reaction mechanism. The key features of this reaction include using pure water as solvent, transition metal- and oxidant-free conditions, and being easily scaled up to gram-scale synthesis. This journal is