68748-92-5Relevant articles and documents
Low-temperature x-ray structural studies of the ester and ether derivatives of cis- and trans-4-tert-butyl cyclohexanol and 2-adamantanol: Application of the variable oxygen probe to determine the relative σ-donor ability of C-H and C-C bonds
Spiniello, Marisa,White, Jonathan M.
, p. 3094 - 3101 (2007/10/03)
Results of low-temperature X-ray structural studies for five cis-, and three trans-4-tert-butyl cyclohexanol, and six 2-adamantanol ester and ether derivatives are reported. Plots of C-OR bond distance against pKa(ROH) for derivatives of axial alcohol (5), equatorial alcohol (6) and 2-adamantanol derivatives (7) give slopes of -2.77 × 10-3, -2.86 × 10-3 and -3.05 × 10-3, respectively. Given that the relative differences in the slopes are modest, no clear distinction can be made about the relative σ-donor ability of a C-H bond and a C-C bond.
Hypobetalipoproteinemic agents. II. Compounds related to 4-(1- adamantyloxy)aniline
Lednicer,Heyd,Emmert,et al.
, p. 69 - 77 (2007/10/06)
While the previously used displacement reaction of sodium 1-adamantyl oxide on 4-fluoronitrobenzene was applicable to the preparation of 4-(1-adamantyloxy) aniline and several related compounds, certain derivatives were not easily accessible by this route
