688-29-9Relevant articles and documents
Atom-economical synthesis of 3,3,3-trifluoropropanal dialkyl acetals through Pd/C catalyzed acetalization of 3,3,3-trifluoropropene
Kang, Jian-Ping,Lu, Ju-You,Li, Yang,Wang, Zhi-Xuan,Mao, Wei,Lu, Jian
, p. 39387 - 39391 (2016/06/01)
A facile and efficient procedure for one-step synthesis of 3,3,3-trifluoropropanal dialkyl acetals from readily available 3,3,3-trifluoropropene (TFP) has been developed. The catalyst can be recycled for 4 times without obvious deactivation. This process provides a novel and atom-economical synthetic strategy for the preparation of functional CF3-containing compounds.
A novel and convenient synthesis of (Z)-3,3,3-trifluoropropenyl alkyl ethers and CF3-substituted propyl acetals as versatile CF3-containing building blocks
Hong, Feng,Hu, Chang-Ming
, p. 57 - 58 (2007/10/03)
A novel and convenient preparation of (Z)-3,3,3-trifluoropropyl alkyl ethers and their further transformation into CF3-substituted propyl acetals is described.
β-PERFLUOROALKYLVINYL ALKYL ETHERS
Pazenok, S. V.,Chaika, E. A.,Gerus, I. I.,Yagupol'skii, L. M.
, p. 1238 - 1241 (2007/10/02)
A convenient method was developed for the synthesis of β-perfluoroalkyl-substituted vinyl ethers by the reaction of vinyl alkyl ethers with perfluoroalkyl iodides in the presence of a palladium catalyst.Fluorine-containing aldehydes and their acetals, in which the perfluoroalkyl radical is separated from the formyl group by a methylene unit, were synthesized from the ethers.These aldehydes can be used for the synthesis of β-perfluoroalkyldicarbocyanines.