6880-10-0Relevant articles and documents
A Novel Cleavage of Allyl Protection
Yu, Biao,Li, Bing,Zhang, Jianbo,Hui, Yongzheng
, p. 4871 - 4874 (2007/10/03)
A novel, efficient, and mild cleavage of allyl protection is developed employing perfluoroalkylation and subsequent elimination.
75. New Triterpenoid N-Acetylglycosides with Molluscicidal Activity from Tetrapleura tetraptera TAUB
Maillard, Marc,Adewunmi, Clement O.,Hostettmann, Kurt
, p. 668 - 674 (2007/10/02)
Activity-guided fractionation of the MeOH extract of the fruits of Tetrapleura tetraptera TAUB. (Mimosaceae) afforded 4 saponins 1-4, which exhibited strong molluscicidal properties against the schistosomiasis-transmitting snails Biomphalaria glabrata.Chemical, enzymatic, and spectral methods (DCI-MS, 1H-NMR, 13C-NMR) showed that they were N-acetylglycosides of oleanolic acid and of echinocystic acid.Apart from saponin 1 (aridanin), previously isolated from this plant, glycosides 2-4 are new naturally occuring compounds.
Entada Saponins (ES) II and IV from the Bark of Entada phaseoloides
Okada, Yoshihito,Shibata, Shoji,Javellana, Ana M. J.,Kamo, Osamu
, p. 1264 - 1269 (2007/10/02)
The structures of entada saponins II and IV, isolated from the bark of Entada phaseoloides (L.) Merrill (Leguminosae), were elucidated as 3-O-2)-α-L-arabinopyranosyl-(1->6)>4)>-2-acetamido-2-deoxy-β-D-glucopyranosyl-28-O-3)-β-D-xylopyranosyl(1->2)>4)>-6-O-((6R)-6-hydroxy-2,6-dimethyl-(2E)-2,7-octadienoyl)-β-D-glucopyranosyl olenolic acid (1) and entagenic acid (3).Keywords - Entada phaseoloides; Leguminosae; triterpene saponin; 13C-NMR chemical shift; entada saponin II; entada saponin IV