6895-56-3

Basic information

• Product Name: 6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane
• Synonyms: bicyclo[3.1.1]heptane, 6-methyl-2-methylene-6-(4-methyl-3-penten-1-yl)-
• CAS NO: 6895-56-3
• Molecular Formula: C₁₅H₂₄
• Molecular Weight: 204.3511
• Mol File: 6895-56-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 260.1°C at 760 mmHg
• Flash Point: 100.8°C
• Density: 0.89g/cm³
• Vapor Pressure: 0.0202mmHg at 25°C
• Refractive Index: 1.494
• CAS DataBase Reference: 6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: 6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane(6895-56-3)
• EPA Substance Registry System: 6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane(6895-56-3)

Safety Data

• Hazardous Substances Data: 6895-56-3(Hazardous Substances Data)

Usage

General Description

6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane is a complex organic compound with a bicyclic structure. It is a derivative of a bicyclo[3.1.1]heptane, which is a bridged bicyclic hydrocarbon. The presence of methyl and methylidene groups in the compound suggests that it is a highly reactive and potentially volatile substance. Additionally, the compound contains a 4-methylpent-3-en-1-yl group, which further contributes to its complex and potentially reactive nature. Due to its complex structure and potential reactivity, this chemical may have various industrial, pharmacological, or other applications. Its exact properties and uses would need to be further explored and studied.

Upstream product

• 97135-66-5 (+/-)-1-oxo-β-trans-bergamotene 
• 152481-50-0 E,E and Z,E-farnesic acid 
• 52536-95-5 (2E,6E)-3,7,11-Trimethyl-dodeca-2,6,10-trienoyl chloride 
• 3796-70-1 trans geranyl acetone 
• 103739-05-5 (E)-7,11-Dimethyl-3-methylene-dodeca-6,10-dienoyl chloride 
• 55050-38-9 (E)-7,11-Dimethyl-3-methylene-dodeca-6,10-dienoic acid 
• 103739-07-7 6-((Z)-1,5-Dimethyl-hexa-1,4-dienyl)-3-methyl-cyclohex-2-enone 
• 103739-04-4 (E)-7,11-Dimethyl-3-oxo-dodeca-6,10-dienoic acid 
• 35315-92-5 trans-6-Methyl-6-(3-oxopropyl)-bicyclo<3.1.1>heptan-3-on 
• 35356-21-9 trans-6-Methyl-6-(4-methyl-3-pentenyl)-bicyclo<3.1.1>heptan-3-on 
• 97135-66-5 (1R,5S,7R)-7-Methyl-2-methylene-7-(4-methyl-pent-3-enyl)-bicyclo[3.1.1]heptan-6-one 
• 462-11-3 (2E,6Z)-3,7,11-trimethyl-2,6,10-dodecatrienoic acid 
• 52536-95-5 (2E,6Z)-3,7,11-Trimethyl-dodeca-2,6,10-trienoyl chloride 
• 97135-66-5 syn-7-methyl-2-methylene-7-(4-methyl-3-pentenyl)bicyclo<3.1.1>heptan-6-one 

Relevant articles and documents

Synthesis of the racemate of (Z)-exo-alpha-bergamotenal, a pheromone component of the white-spotted spined bug, Eysarcoris parvus Uhler.

The racemate of (Z)-exo-alpha-bergamotenal, a sex pheromone component of the white-spotted spined bug, was synthesized from racemic exo-alpha-bergamotene by a five-step sequence involving regioselective epoxidation and (Z)-selective Wittig olefination reactions. The 1H- and 13C-NMR spectra of the synthetic sample were identical with those of the natural material.

SIMPLE SYNTHESIS OF (+)-β-TRANS-BERGAMOTENE

(+)-β-trans-Bergamotene (4) has been synthesized in five steps from geranylacetone using intramolecular ketene-olefin cycloadditon as a key step.

Intramolecular Cycloadditions of Ketenes. 2. Synthesis of Crysanthenone, β-Pinene, β-cis-Bergamotene, and β-trans-Bergamotene

Vinylketenes prepared from geranoyl and farnesoyl chloride by treatment with triethylamine react to give bicycloheptanones which can be converted to β-pinene and the β-bergamotenes by Wolff-Kishner reduction.