68971-91-5Relevant articles and documents
Illuminating Stannylation
Sakamoto, Kyoka,Nagashima, Yuki,Wang, Chao,Miyamoto, Kazunori,Tanaka, Ken,Uchiyama, Masanobu
supporting information, p. 5629 - 5635 (2021/05/04)
We have developed photoboosted stannylation reactions of terminal alkynes (linear-selective hydrostannylation) and fluoroarenes (defluorostannylation), in which the stannyl anion is photoexcited to an excited triplet (T1) stannyl diradical species. This u
Stannyl-Lithium: A Facile and Efficient Synthesis Facilitating Further Applications
Wang, Dong-Yu,Wang, Chao,Uchiyama, Masanobu
supporting information, p. 10488 - 10491 (2015/09/28)
We have developed a highly efficient, practical, polycyclic aromatic hydrocarbon (PAH)-catalyzed synthesis of stannyl lithium (Sn-Li), in which the tin resource (stannyl chloride or distannyl) is rapidly and quantitatively transformed into Sn-Li reagent at room temperature without formation of any (toxic) byproducts. The resulting Sn-Li reagent can be stored at ambient temperature for months and shows high reactivity toward various substrates, with quantitative atom efficiency.
FLUORINATION OF ORGANIC COMPOUNDS
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Page/Page column 32; 33, (2010/07/10)
Methods for fluorinating organic compounds are described herein.