68991-97-9Relevant articles and documents
Method for preparation of cyclic myrac aldehydes from myrac aldehyde catalyzed by zinc-containing ionic liquid
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Paragraph 0023-0025; 0027-0030; 0040-0042, (2019/04/30)
The invention provides a novel method for catalyzing cyclization reaction of myrac aldehyde for conversion to cyclic myrac aldehydes by using a Lewis acidic ionic liquid as a catalyst. According to the method, by using a zinc-containing ionic liquid as a catalyst and under the mild condition, 4-(4-methyl-3-pentenyl)-3-cyclohexenal(p-myrac aldehyde) and 3-(4-methyl-3-pentenyl)-3-cyclohexenal (m-myrac aldehyde) undergo selective cyclization to prepare cyclic myrac aldehydes (1,2,3,4,5,6,7,8-octahydro-,8,8-dimethyl-2-naphthaldehyde and 1,2,3,4,5,6,7,8-octahydro-5,5-dimethyl-2-naphthaldehyde). Incomparison with a traditional cyclic myrac aldehydes production method, the invention has the following distinctive characteristics: the use of a volatile organic solvent is avoided in the reaction; the reaction condition is mild; the target product has high selectivity, and the reaction is rapid; after the reaction, the ionic liquid catalyst and the product are automatically layered and are convenient to separate; the ionic liquid catalyst is recyclable; generation of a waste acid solution by traditional catalysis is avoided; and the method is environmentally friendly.
A catalytic citrus reticulata blue aldehyde supported upper collector [...] method of preparation (by machine translation)
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Paragraph 0021-0024; 0031-0036, (2019/04/30)
The invention provides a to Re2 O7 /AC as catalyst, the catalytic [...][...] reaction conversion for the new method. The method to the organic small molecule reagent as reaction solvent, in order to Re2 O7 /AC as catalyst, under mild conditions will be 4 - (4 - methyl - 3 - pentenyl) - 3 - ring hexenal (citrus reticulata blue aldehyde to position) and 3 - (4 - methyl - 3 - pentenyl) - 3 - ring hexenal (meta-citrus reticulata blue aldehyde) selection cyclized preparation [...] (1, 2, 3, 4, 5, 6, 7, 8 - octahydro -, 8, 8 - dimethyl - 2 - [...] and 1, 2, 3, 4, 5, 6, 7, 8 - octahydro - 5, 5 - dimethyl - 2 - [...]). Compared with the traditional [...] production method, the invention feature: mild reaction conditions, selectivity of target product is high, the reaction speed is fast; the catalyst is activated carbon load of the upper collector, can be recycled, thereby avoiding the generation of traditional catalytic waste acid, environment-friendly. (by machine translation)
Precursors for fragrant ketones and fragrant aldehydes
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, (2008/06/13)
The present invention refers to fragrance precursors of formula I for a fragrant ketone of formula II and one or more fragrant aldehydes or ketones of formula III and IV, These fragrance precursors are useful in perfumery, especially in the fine and functional perfumery.