69008-03-3Relevant articles and documents
Synthesis of naphthyl C-glycosides of rearranged tri-O-benzyl-2-deoxy-D- glucose
Brimble, Margaret A.,Brenstrum, Timothy J.
, p. 1107 - 1110 (2000)
C-Glycosylation of 3-bromonaphthol 4 with benzyl-protected glycosyl donor 19 afforded rearranged bicyclic acetal 24 in which the glycosyl donor had undergone an unusual 1,6-hydride shift. Use of the regioisomeric 2- bromonaphthol 6 with the same glycosyl donor 19 afforded the expected β-C- glycoside 22. (C) 2000 Elsevier Science Ltd.