6901-13-9 Usage
Description
[7S-(7alpha,7bbeta,10abeta)]-N-(5,6,7,7b,8,10a-hexahydro-1,2,3,9-tetramethoxy-8-oxobenzo[a]cyclopenta[3,4]cyclobuta[1,2-c]cyclohepten-7-yl)acetamide is a complex organic compound with a unique molecular structure. It is characterized by its hexahydro-1,2,3,9-tetramethoxy-8-oxobenzo[a]cyclopenta[3,4]cyclobuta[1,2-c]cyclohepten-7-yl)acetamide backbone and its 7S-(7alpha,7bbeta,10abeta) stereochemistry. [7S-(7alpha,7bbeta,10abeta)]-N-(5,6,7,7b,8,10a-hexahydro-1,2,3,9-tetramethoxy-8-oxobenzo[a]cyclopenta[3,4]cyclobuta[1,2-c]cyclohepten-7-yl)acetamide is likely to have specific applications in various fields due to its unique chemical properties.
Uses
Used in Pharmaceutical Industry:
[7S-(7alpha,7bbeta,10abeta)]-N-(5,6,7,7b,8,10a-hexahydro-1,2,3,9-tetramethoxy-8-oxobenzo[a]cyclopenta[3,4]cyclobuta[1,2-c]cyclohepten-7-yl)acetamide is used as a potential therapeutic agent for various medical conditions. Its unique molecular structure and stereochemistry allow it to interact with specific biological targets, making it a promising candidate for the development of new drugs.
Used in Chemical Research:
[7S-(7alpha,7bbeta,10abeta)]-N-(5,6,7,7b,8,10a-hexahydro-1,2,3,9-tetramethoxy-8-oxobenzo[a]cyclopenta[3,4]cyclobuta[1,2-c]cyclohepten-7-yl)acetamide is also used as a research tool in the field of organic chemistry. Its complex structure and unique properties make it an interesting subject for studying various chemical reactions and mechanisms, which can lead to the discovery of new synthetic methods and applications.
Used in Material Science:
The unique molecular structure of [7S-(7alpha,7bbeta,10abeta)]-N-(5,6,7,7b,8,10a-hexahydro-1,2,3,9-tetramethoxy-8-oxobenzo[a]cyclopenta[3,4]cyclobuta[1,2-c]cyclohepten-7-yl)acetamide may also have potential applications in the field of material science. Its properties could be exploited to develop new materials with specific characteristics, such as improved stability, reactivity, or selectivity.
References
Santavy, Collect. Czech. Chem. Commun., 16,665 (1951)
Santavy, Pharm. Zent., 96, 307 (1957)
Yusupov, Sadykov, Tr. Nauch. Tashkent. Gos. Univ., 203, 3, 15 (1962)
YUSUpOY, SadykoY, J. Gen. Chem. USSR, 34, 1672 (1964)
Yusupov, Sadykov, Tr. Nauch. Tashkent. Gos. Univ., 286,11,56 (1966)
Chommedov, Yusupov, Sadykov, Khim. Prir. Soedin., 6, 82, 275 (1970)
Trozyan, Yusupov, Sadykov, ibid, 7,541 (1971)
Santavy, Tr. Nauchi. Tashkent, 11 (1972)
Check Digit Verification of cas no
The CAS Registry Mumber 6901-13-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,9,0 and 1 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 6901-13:
(6*6)+(5*9)+(4*0)+(3*1)+(2*1)+(1*3)=89
89 % 10 = 9
So 6901-13-9 is a valid CAS Registry Number.
6901-13-9Relevant articles and documents
Chapman et al.
, p. 806,811 (1963)
Colchicine-protein interactions revealed by transient absorption spectroscopy after in situ photoisomerization to lumicolchicines
Bartovsky, Pavel,Tormos, Rosa,Miranda, Miguel A.
experimental part, p. 305 - 308 (2010/03/03)
Irradiation of colchicine (COL) inside serum albumins (SAs) at 350 nm, results in an efficient isomerization to β- and γ-lumicolchicines (LCs). Laser flash photolysis of pre-irradiated COL/SA complexes leads to detection of long-lived LC-derived triplet excited states (λmax = 370 and 600 nm, τT > 10 μs).
Does the photochemical conversion of colchicine into lumicolchicines involve triplet transients? A solvent dependence study.
Nery,Quina,Moreira Jr,Medeiros,Baader,Shimizu,Catalani,Bechara
, p. 213 - 218 (2007/10/03)
beta- and gamma-lumicolchicines are photoproducts formed by the cycloisomerization of the tropolone ring of colchicine (COL) alkaloids. The mechanism of the photoconversion, suggested to involve the triplet state, is examined here by studying the effect of the solvent polarity on the lumicolchicine photoisomer ratio. Triplet COL, detected by laser flash photolysis, is quenched by oxygen, but not by transtilbene or 1-methylnaphtalene. Neither the quantum yield of conversion of COL nor the photoproduct ratio was altered by the presence of oxygen. Likewise, energy transfer to COL from triplet acetone produced by either isobutanal/horseradish peroxidase system or tetramethyldioxetane thermolysis failed to provoke photoreaction of COL. Our data argue against the intermediacy of a COL triplet state in the photoisomerization and stress on the role of specific solvent-solute interactions in determining the partitioning of excited singlet state into the beta- and gamma-isomer formation.
