690211-39-3

Basic information

• Product Name: (1R,6R,9S)-2-Isopropenyl-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid benzyl ester
• Synonyms: (1R,6R,9S)-2-Isopropenyl-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid benzyl ester
• CAS NO: 690211-39-3
• Molecular Weight: 297.397
• Mol File: 690211-39-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,6R,9S)-2-Isopropenyl-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,6R,9S)-2-Isopropenyl-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid benzyl ester(690211-39-3)
• EPA Substance Registry System: (1R,6R,9S)-2-Isopropenyl-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid benzyl ester(690211-39-3)

Safety Data

• Hazardous Substances Data: 690211-39-3(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 690211-37-1 (2R,5R)-5-but-3-enyl-2-ethynylpyrrolidine-1-carboxylic acid 1-benzyl ester 
• 690211-38-2 (2R)-but-3-enyl-(5R)-prop-1-ynylpyrrolidine-1-carboxylic acid 1-benzyl ester 
• 760968-59-0 (2R)-but-3-enyl-(5R)-2-(1-methylsiletan-1-ylethynyl)pyrrolidine-1-carboxylic acid benzyl ester 
• 690211-35-9 (2R)-benzyloxycarbonylamino-5-oxonon-8-enoic acid methyl ester 
• 690211-34-8 1-benzyl 2-methyl (R)-5-oxopyrrolidine-1,2-dicarboxylate 
• 64700-65-8 methyl (2R)-pyroglutamate 

Downstream Products

• 690211-40-6 (+)-(1R)-2-(1,2-dihydroxy-1-methylethyl)-9-benzyloxycarbonyl-9-azabicyclo[4.2.1]-2-nonene 
• 64285-06-9 anatoxin-a 
• 120692-41-3 (+)-(1R)-2-acetyl-9-benzyloxycarbonyl-9-azabicyclo[4.2.1]-2-nonene 
• 690211-40-6 (1R,6R,9S)-2-(1,2-Dihydroxy-1-methyl-ethyl)-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid benzyl ester 
• 120692-41-3 (1R,6R,9S)-2-Acetyl-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid benzyl ester 

Relevant articles and documents

Application of intramolecular enyne metathesis to the synthesis of aza[4.2.1]bicyclics: Enantiospecific total synthesis of (+)-anatoxin-a

A concise synthesis of the potent nAChR agonist (4)-anatoxin-a (1) has been completed in a series of only nine chemical operations and 27% overall yield from commercially available D-methyl pyroglutamate (4). The synthesis features a novel procedure for t