69025-33-8Relevant articles and documents
Chiral Ligands in Hypervalent Iodine Compounds: Synthesis and Structures of Binaphthyl-Based λ3-Iodanes
Zhang, Huaiyuan,Cormanich, Rodrigo A.,Wirth, Thomas
supporting information, (2021/12/22)
Several novel binaphthyl-based chiral hypervalent iodine(III) reagents have been prepared and structurally analysed. Various asymmetric oxidative reactions were applied to evaluate the reactivities and stereoselectivities of those reagents. Moderate to excellent yields were observed; however, very low stereoselectivities were obtained. NMR experiments indicated that these reagents are very easily hydrolysed in either chloroform or DMSO solvents leading to the limited stereoselectivities. It is concluded that the use of chiral ligands is an unsuccessful way to prepare efficient stereoselective iodine(III) reagents.
Preparation and characterization of a novel Wells-Dawson heteropolyacid-based magnetic inorganic-organic nanohybrid catalyst H 6P2W18O62/pyridino-Fe 3O4 for the efficient synthesis of 1-ami
Tayebee, Reza,Amini, Mostafa M.,Rostamian, Hooriyeh,Aliakbari, Azam
, p. 1550 - 1563 (2014/01/06)
A novel magnetic inorganic-organic nanohybrid material H6P 2W18O62/pyridino-Fe3O4 (HPA/TPI-Fe3O4) was fabricated and performed as an efficient, eco-friendly, and highl
