6907-73-9

Basic information

• Product Name: N-(A-METHYLBENZYLIDENE)ISOPROPYLAMINE
• Synonyms: N-(A-METHYLBENZYLIDENE)ISOPROPYLAMINE
• CAS NO: 6907-73-9
• Molecular Formula: C₁₁H₁₅N
• Molecular Weight: 161.24
• Mol File: 6907-73-9.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 215.4°C at 760 mmHg
• Flash Point: 75.6°C
• Appearance: /
• Density: 0.88g/cm³
• Vapor Pressure: 0.216mmHg at 25°C
• Refractive Index: 1.492
• CAS DataBase Reference: N-(A-METHYLBENZYLIDENE)ISOPROPYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(A-METHYLBENZYLIDENE)ISOPROPYLAMINE(6907-73-9)
• EPA Substance Registry System: N-(A-METHYLBENZYLIDENE)ISOPROPYLAMINE(6907-73-9)

Safety Data

• Hazardous Substances Data: 6907-73-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H15N/c1-9(2)12-10(3)11-7-5-4-6-8-11/h4-9H,1-3H3

Upstream product

• 75-31-0 isopropylamine 
• 98-86-2 acetophenone 

Downstream Products

• 6303-82-8 1-phenylhexane-1,5-dione 
• 68165-44-6 Benzoyl-5-nonandion-2,8 
• 148564-68-5 1-isopropyl-5-phenyl-2,3-pyrrolinedione 
• 75784-80-4 Isopropyl-(1-phenyl-vinyl)-trimethylsilanyl-amine 
• 138877-94-8 1,3-Diisopropyl-5-methyl-5-phenyl-4-(isopropylimino)-2-thioxo-1,3-diazolidine 
• 947504-29-2 (E)-N-(2,2-difluoro-1-phenylethylidene)isopropylamine 
• 450-95-3 2-fluoroacetophenone 
• 947503-98-2 (E)-N-(2-chloro-2-fluoro-1-phenylethylidene)isopropylamine 
• 947504-09-8 (E)-N-(2-bromo-2-fluoro-1-phenylethylidene)isopropylamine 
• 947504-12-3 N-(2-chloro-2-fluoro-1-phenylethyl)-N-isopropylamine 
• 148564-72-1 4-chloro-1-isopropyl-5-phenyl-2,3-pyrrolinedione 
• 148564-73-2 4-bromo-1-isopropyl-5-phenyl-2,3-pyrrolinedione 

Relevant articles and documents

Montmorillonite as a heterogeneous catalyst in the efficient, mild and one pot synthesis of Schiff bases under solvent-free conditions

A mild and efficient method has been reported for preparation of Schiff base ligands through condensation reaction of various aromatic aldehydes and ketones with different aromatic amines in the presence of montmorillonite as a heterogeneous catalyst under solvent free conditions. The advantages of this friendly, economically, environmentally and mild method are such as; simplicity of the reaction procedure, reusability of catalyst, simple work-up, high product yields and very short reaction times.

Nucleophilic trifluoromethylation of imines under acidic conditions

A general method for the trifluoromethylation of imines by using Me 3SiCF3 under acidic conditions is described. The reaction is promoted by hydrofluoric acid generated in situ from KHF2 and either TFA or TfOH. A new chemoselectivity pattern was achieved, as the C=N bond was found to be more reactivate than the carbonyl group. The trifluoromethylation reaction is believed to proceed by concerted transfer of the CF3 group from the silicon atom to the iminium electrophile. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

New entries toward 3,3-difluoropiperidines

(Chemical Equation Presented) Difluoropiperidines attract considerable interest from organic and medicinal chemists, but their synthesis is often problematic. This paper describes a new synthetic pathway toward valuable 3,3-difluoropiperidines starting fr