69209-65-0Relevant articles and documents
Liquid crystalline properties of azobenzenes: I. 4-methoxy-, 4-ethoxy-, 4-propoxy-and 4-butoxy-4′-alkyloxyazobenzenes
Galewski,Hofmanska,Zielinska
, p. 1357 - 1371 (2007/10/03)
Liquid crystalline properties of four series of azobenzenes, 4-methoxy-4-alkyloxyazobenzenes (azo-1-n), 4-ethoxy-4′-alkyloxyazobenzenes (azo-2-n), 4-propoxy-4′al-kyloxyazobenzenes (azo-3-n) and 4-butoxy-4′-alkyloxyazobenzenes (azo-4-n), were investigated. By polarizing microscopy nematic and smectic C mesophases were detected. By DSC and TOA thermo-optics the parameters of phase transitions were measured. A typical odd-even effect of the clearing temperature was found. No smectic phase was detected in the first three series, even for the longest alkyloxy chains. The smectic C appears for the first time in the butoxy family, starting from the undecyloxyl derivative. In each series a polymorphism in the solid state was detected, especially significant in the propoxy and butoxy family, that was explained in terms of the ODIC phases.