69257-97-2Relevant articles and documents
Efficient intermolecular [2 + 2 + 2] alkyne cyclotrimerization in aqueous medium using a ruthenium(IV) precatalyst
Cadierno, Victorio,Garcia-Garrido, Sergio E.,Gimeno, Jose
, p. 15094 - 15095 (2007/10/03)
The dimeric bis(allyl)-ruthenium(IV) complex [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] (C10H16 = 2,7-dimethylocta-2,6-diene-1,8-diyl) was found to catalyze efficiently the [2 + 2 + 2] cyclization of terminal and internal alkynes in aqueous medium. Copyright
Diazadienes as Controlling Ligands in Homogeneous Catalysis, VIII. Catalytic Trimerization of Substituted Acetylene Carbonic Acid Esters and Isolation of an Acetylene Dicarbonic Acid Ester Diazadiene Nickel(0) Adduct
Diercks, Rainer,Dieck, Heindirk tom
, p. 180 - 184 (2007/10/02)
Nickel(0) complexes of diazadienes (dad = RN=CR'-CR'=NR) catalyse the trimerization of esters of 2-butynoic acid, phenylpropynoic acid and butynedioic acid to give hexasubstituted benzenes with the unsymmetrical esters 2 as the main products.A primary add