69267-83-0

Basic information

• Product Name: tris(di-n-butyldithiocarbamato)-phosphorus(III)
• Synonyms: tris(di-n-butyldithiocarbamato)-phosphorus(III)
• CAS NO: 69267-83-0
• Molecular Weight: 644.116
• Mol File: 69267-83-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tris(di-n-butyldithiocarbamato)-phosphorus(III)(CAS DataBase Reference)
• NIST Chemistry Reference: tris(di-n-butyldithiocarbamato)-phosphorus(III)(69267-83-0)
• EPA Substance Registry System: tris(di-n-butyldithiocarbamato)-phosphorus(III)(69267-83-0)

Safety Data

• Hazardous Substances Data: 69267-83-0(Hazardous Substances Data)

Upstream product

• 2391-80-2 Di-n-butylammonium di-n-butyldithiocarbamate 

Relevant articles and documents

Thermochemical properties of chelates of di-n-butyldithiocarbamate with phosphorus-group elements

The standard molar enthalpies of formation of crystalline tris(di-n-butyldithiocarbamato)E(III), (E = P, As, Sb, or Bi), determined at 298.15 K by solution-reaction calorimetry, are -(705.5 +/- 7.3), -(443.1 +/- 5.4), -(526.2 +/- 2.5), and -(530.7 +/- 5.5) kJ*mol-1, respectively.The enthalpies of sublimation: (136 +/- 3), (128 +/- 3), (179 +/- 3), and (202 +/- 3) kJ*mol-1, were estimated.From the enthalpies of formation of the gaseous complexes, the homolytic and heterolytic mean standard molar element-sulphur bond enthalpies were calculated.These values are correlated with element-sulphur bond distances, and a larger phosphorus- sulphur bond enthalpy reflects a better overlap of d orbitals in bonding formation.