69278-45-1

Basic information

• Product Name: Benzene, (2-methoxy-2-methylpropyl)-
• CAS NO: 69278-45-1
• Molecular Formula: C11H16O
• Molecular Weight: 164.247
• Mol File: 69278-45-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, (2-methoxy-2-methylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-methoxy-2-methylpropyl)-(69278-45-1)
• EPA Substance Registry System: Benzene, (2-methoxy-2-methylpropyl)-(69278-45-1)

Safety Data

• Hazardous Substances Data: 69278-45-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 3290-53-7 2-methyl-1-phenyl-2-propene 
• 768-49-0 (2-methyl-1-propenyl)-benzene 
• 1754-74-1 2-chloro-2-methyl-1-phenylpropane 
• 100-86-7 2-Methyl-1-phenyl-2-propanol 
• 74-88-4 methyl iodide 
• 123622-12-8 2-(benzotriazol-1-yl)-2-methoxypropane 
• 6921-34-2 benzylmagnesium chloride 
• 42085-79-0 2-methoxy-2-methyl-1-phenyl-propylmercury ⁽¹⁺⁾; chloride 

Downstream Products

• 588-46-5 N-(phenylmethyl)acetamide 
• 100-52-7 benzaldehyde 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 645-59-0 dihydrocinnamonitrile 
• 79-20-9 acetic acid methyl ester 
• 1754-74-1 2-chloro-2-methyl-1-phenylpropane 
• 1403251-37-5 N-(1,3-dioxoisoindolin-2-yl)-N-(4-(2-methoxy-2-methylpropyl)phenyl)acetamide 
• 1403251-38-6 N-(1,3-dioxoisoindolin-2-yl)-N-(2-(2-methoxy-2-methylpropyl)phenyl)acetamide 

Relevant articles and documents

ANODIC FUNCTIONALIZATION OF OLEFINS IN ALCOHOLS IN THE PRESENCE OF HALIDE SALTS

Electrolysis of conjugated, unbranched arylolefins in the presence of alkali metal halides in alcohols affords 1-aryl-2-bromoketals in 60-90percent yields.Under these conditions, 2-methyl-1-phenylprop-1-ene is converted into 1-bromo-2-methyl-1-phenylprop-1-ene in 80percent yield, and arylolefins with no benzylidene hydrogens give 1-aryl-1-alkoxy-2-bromoalkanes.

Reactions of 1-(α-Alkoxyalkyl)- and 1-(α-(Aryloxy)alkyl)benzotriazoles with the Grignard Reagents. A New and Versatile Method for the Preparation of Ethers

1-(α-Alkoxyalkyl)benzotriazoles deriving from aldehydes (other than formaldehyde), or from ketones, react with Grignard reagents at 110 deg C to provide a high-yielding, general synthesis of dialkyl and aryl ethers.Under similar conditions, 1-(alkoxymethyl)- and 1-((aryloxy)methyl)benzotriazoles give, by a different cleavage pattern of the N-C-O grouping, 1-alkylbenzotriazoles and N,N'-dialkyl-o-phenylenediamines.The 1-(α-alkoxyalkyl)benzotriazoles are easily prepared: (a) by condensation of benzotriazole, an aldehyde, and an alcohol under water-removing conditions; (b) by condensation of a 1-(α-chloroalkyl)benzotriazole with a sodium or potassium alkoxide or aryloxide; and (c) by condensatioon of an acetal or a ketal with benzotriazole.All the 1-(α-alkoxyalkyl)benzotriazoles and dialkyl or alkyl aryl ethers obtained were fully characterized by their 1H and 13C NMR spectra.

Some Methoxysilanes, Disiloxanes and Digermoxanes with Effectiveness of Odour. Sila-Substituted Perfumes, III.

The odour of the formerly unknown compounds benzyldimethylmethoxysilane 2a (flower-honey like with a minty component; intensity middle), bis(benzyl)tetramethyldisiloxane 4a (flowerlike; very weak) and bis(benzyl)tetramethyldigermoxane 9 (almond-soapy like; relatively strong) was registered and compared with related compounds (for example benzyldimethylmethoxymethane 5a, camphor-radish like).Information is given on preparation and analytical and structural investigation of several methoxysilanes and disioxanes with benzyl and phenethyl groups (compare equations and experimental part). - Keywords: Digermoxanes; Disiloxanes; Methoxysilanes; Odour; Sila-perfumes