69297-03-6

Basic information

• Product Name: (1'S,2'R,4'S,2Z,4E)-5-(1',2'-Epoxy-4'-hydroxy-2',6',6'-trimethylcyclohexyl)-3-methylpenta-2,4-diensaeure-methylester
• Synonyms: (1'S,2'R,4'S,2Z,4E)-5-(1',2'-Epoxy-4'-hydroxy-2',6',6'-trimethylcyclohexyl)-3-methylpenta-2,4-diensaeure-methylester
• CAS NO: 69297-03-6
• Molecular Weight: 280.364
• Mol File: 69297-03-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1'S,2'R,4'S,2Z,4E)-5-(1',2'-Epoxy-4'-hydroxy-2',6',6'-trimethylcyclohexyl)-3-methylpenta-2,4-diensaeure-methylester(CAS DataBase Reference)
• NIST Chemistry Reference: (1'S,2'R,4'S,2Z,4E)-5-(1',2'-Epoxy-4'-hydroxy-2',6',6'-trimethylcyclohexyl)-3-methylpenta-2,4-diensaeure-methylester(69297-03-6)
• EPA Substance Registry System: (1'S,2'R,4'S,2Z,4E)-5-(1',2'-Epoxy-4'-hydroxy-2',6',6'-trimethylcyclohexyl)-3-methylpenta-2,4-diensaeure-methylester(69297-03-6)

Safety Data

• Hazardous Substances Data: 69297-03-6(Hazardous Substances Data)

Upstream product

• 51318-62-8 ethyl 4-bromo-3-methylcrotonate 
• 186581-53-3 diazomethane 
• 88852-29-3 (-)-(2Z,4E)-5-(1',2'-epoxy-2',6',6'-trimethylcyclohexyl)-3-methyl-2,4-pentadienoic acid 

Downstream Products

• 8066-07-7 (1'S,2'R,4'S,2Z,4E)-(1',2'-epoxy-4'-hydroxy-2',6',6'-trimethylcyclohexyl)-3-methylpenta-2,4-dienal 

Relevant articles and documents

Convenient Syntheses of Optically Active Abscisic Acid and Xanthoxin

The Reformatzky reaction of 3-(bromomethyl)crotonate with an optically active epoxycyclohexane aldehyde derivative (3), followed by dehydration, gave the chiral dienoic acid (6) stereospecifically.The product was derived to optically active abscisic acid (1) and xanthoxin (2) successfully.