6936-14-7

Basic information

• Product Name: 4-(4-methylphenyl)-1,2-dihydronaphthalene
• CAS NO: 6936-14-7
• Molecular Formula: C₁₇H₁₆
• Molecular Weight: 220.3089
• Mol File: 6936-14-7.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 340.7°C at 760 mmHg
• Flash Point: 169.6°C
• Density: 1.059g/cm³
• Vapor Pressure: 0.000166mmHg at 25°C
• Refractive Index: 1.607
• CAS DataBase Reference: 4-(4-methylphenyl)-1,2-dihydronaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(4-methylphenyl)-1,2-dihydronaphthalene(6936-14-7)
• EPA Substance Registry System: 4-(4-methylphenyl)-1,2-dihydronaphthalene(6936-14-7)

Safety Data

• Hazardous Substances Data: 6936-14-7(Hazardous Substances Data)

Upstream product

• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 5720-05-8 4-methylphenylboronic acid 
• 123994-49-0 3,4-dihydro-1-naphthyl triflate 
• 101552-29-8 1-methyl-4-(1-phenylbuta-1,3-dienyl)benzene 
• 27331-24-4 1-phenyl-4-(p-tolyl)buta-1,3-diene 
• 1064664-64-7 1-methyl-4-(4-phenylbut-1-yn-1-yl)benzene 
• 5142-75-6 tri(p-tolyl)bismuth 
• 149512-01-6 1,2-dihydro-4-iodonaphthalene 
• 17336-59-3 1-tetralone tosylhydrazone 
• 19455-84-6 3,4-dihydronaphthalen-1-yl acetate 
• 106-38-7 para-bromotoluene 

Downstream Products

• 109036-36-4 1,2-epoxy-1-p-tolyl-1,2,3,4-tetrahydro-naphthalene 
• 27331-34-6 1-(4-methylphenyl)naphthalene 
• 108973-38-2 3-nitro-4-p-tolyl-1,2-dihydro-naphthalene 
• 19723-03-6 7-methyl-1-phenylnaphthalene 
• 29304-61-8 6-methyl-1-phenylnaphthalene 
• 29304-62-9 6-methyl-4-phenyl-1,2-dihydro-naphthalene 
• 29304-60-7 7-methyl-4-phenyl-1,2-dihydronaphthalene 
• 108973-58-6 1-p-tolyl-1,2,3,4-tetrahydro-[2]naphthylamine 
• 109036-39-7 1-(p-tolyl)-3,4-dihydronaphthalen-2(1H)-one 

Relevant articles and documents

Conversion of Carbonyl Compounds to Olefins via Enolate Intermediate

A general and efficient protocol to synthesize substituted olefins from carbonyl compounds via nickel catalyzed C—O activation of enolates was developed. Besides ketones, aldehydes were also suitable substrates for the presented catalytic system to produce di- or tri- substituted olefins. It is worth noting that this approach exhibited good tolerance to highly reactive tertiary alcohols, which could not survive in other reported routes for converting carbonyl compounds to olefins. This method also showed good regio- and stereo-selectivity for olefin products. Preliminary mechanistic studies indicated that the reaction was accomplished through nickel catalyzed C—O activation of enolates, thus offering helpful contribution to current enol chemistry.

Olefin Preparation via Palladium-Catalyzed Oxidative De-Azotative and De-Sulfitative Internal Cross-Coupling of Sulfonylhydrazones

A novel reactivity of sulfonylhydrazones under Pd catalysis is described, where SO2 and N2 are formally extruded to afford the product of an apparent internal coupling reaction. The reaction is effective with both carbocyclic and heterocyclic aromatic precursors.

Atom-efficient vinylic arylations with triarylbismuths as substoichiometric multicoupling reagents under palladium catalysis

The first atom-efficient arylation of vinylic iodides was achieved by using triarylbismuths as substoichiometric multicoupling reagents under palladium catalysis. Vinylic iodides were efficiently coupled with electronically divergent triarylbismuths to furnish the corresponding arylated products in short reaction times.