69371-59-1

Basic information

• Product Name: 5-Hexen-2-one, 6-phenyl-
• CAS NO: 69371-59-1
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 69371-59-1.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 5-Hexen-2-one, 6-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexen-2-one, 6-phenyl-(69371-59-1)
• EPA Substance Registry System: 5-Hexen-2-one, 6-phenyl-(69371-59-1)

Safety Data

• Hazardous Substances Data: 69371-59-1(Hazardous Substances Data)

Upstream product

• 109-49-9 5-Hexen-2-one 
• 5720-07-0 4-methoxyphenylboronic acid 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 100-52-7 benzaldehyde 
• 1493-13-6 trifluorormethanesulfonic acid 
• 105-45-3 acetoacetic acid methyl ester 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 673-32-5 1-Phenylprop-1-yne 
• 67-64-1 acetone 
• 98-80-6 phenylboronic acid 
• 104-54-1 3-Phenylpropenol 
• 57582-46-4 cinnamyl 3-oxobutanoate 
• 112163-00-5 (+/-)-1-phenylallyl acetoacetate 
• 4392-24-9 Cinnamyl bromide 

Downstream Products

• 127047-14-7 5-hydroxy-1-phenyl-hexene-⁽¹⁾ 
• 134025-31-3 N-Methoxy-1-phenyl-1-hexen-5-one oxime 
• 134038-98-5 N-Methyl-1-methyl-5-phenylpent-4-enylamine 
• 38488-04-9 (2R*,6R*)-2-methyl-6-phenyltetrahydro-2H-pyran 
• 182194-89-4 Toluene-4-sulfonic acid (E)-1-methyl-5-phenyl-pent-4-enyl ester 
• 134025-21-1 cis-2-Benzyl-1,5-dimethylpyrrolidine 
• 134025-26-6 N-Methoxy-1-methyl-5-phenylpent-4-enylamine 
• 134038-99-6 2-Benzoyl-1-methoxy-5-methylpyrrolidine 
• 14171-89-2 1-phenyl-5-hexanone 

Relevant articles and documents

Synthesis of Cyclic β-Silylalkenyl Triflates via an Alkenyl Cation Intermediate

Trimethylsilylalkyne derivatives are transformed into cyclic β-silylalkenyl triflates through cationic cyclization and subsequent trapping of the alkenyl cation by a triflate anion. β-Silylcyclohexenyl triflates and 3-trimethylsilyl-1,4-dihydronaphth-2-yl

A New Route to Phenols: Palladium-Catalyzed Cyclization and Oxidation of γ,δ-Unsaturated Ketones

We report a new strategy for the synthesis of phenols from acyclic unsaturated ketones in one pot. The reaction proceeds by palladium-catalyzed carbopalladation of an alkene with the enol form of the tethered ketone, generating a substituted cyclohexanone. Upon introduction of a terminal oxidant a palladium-catalyzed oxidation ensues to give the desired phenol. This approach allows the programming of phenol substituents on the acyclic substrate and therefore circumvents the limitations inherent in traditional syntheses of phenols.

Pd(0)-catalyzed 1,1-diarylation of ethylene and allylic carbonates

An efficient protocol for the one-step synthesis of biologically relevant 1,1-diarylalkanes has been described. This reaction introduces two different aryl groups across the terminal end of simple feedstock alkenes such as ethylene and allylic carbonates.