69477-90-3

Basic information

• Product Name: 3-Hydroxy-5,5-dimethyl-2-(1-methyl-2-nitro-2-phenylsulfanyl-ethyl)-cyclohex-2-enone
• Synonyms: 3-Hydroxy-5,5-dimethyl-2-(1-methyl-2-nitro-2-phenylsulfanyl-ethyl)-cyclohex-2-enone
• CAS NO: 69477-90-3
• Molecular Weight: 335.424
• Mol File: 69477-90-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Hydroxy-5,5-dimethyl-2-(1-methyl-2-nitro-2-phenylsulfanyl-ethyl)-cyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Hydroxy-5,5-dimethyl-2-(1-methyl-2-nitro-2-phenylsulfanyl-ethyl)-cyclohex-2-enone(69477-90-3)
• EPA Substance Registry System: 3-Hydroxy-5,5-dimethyl-2-(1-methyl-2-nitro-2-phenylsulfanyl-ethyl)-cyclohex-2-enone(69477-90-3)

Safety Data

• Hazardous Substances Data: 69477-90-3(Hazardous Substances Data)

Upstream product

• 67808-90-6 1-nitro-1-(phenylthio)-2-propanol 
• 60595-16-6 (phenylthio)nitromethane 
• 103-04-8 (phenylthio)acetic acid 
• 67808-91-7 (Z)-1-nitro-1-(phenylthio)propene 
• 126-81-8 dimedone 

Downstream Products

• 69477-91-4 (2S,3S)-2-Benzenesulfinyl-3,6,6-trimethyl-3,5,6,7-tetrahydro-2H-benzofuran-4-one 
• 69477-91-4 (2R,3S)-2-Benzenesulfinyl-3,6,6-trimethyl-3,5,6,7-tetrahydro-2H-benzofuran-4-one 
• 67808-93-9 trans-3,6,6-trimethyl-2-phenylsulfanyl-3,5,6,7-tetrahydro-2H-benzofuran-4-one 
• 67808-92-8 cis-3,6,6-trimethyl-2-phenylsulfanyl-3,5,6,7-tetrahydro-2H-benzofuran-4-one 

Relevant articles and documents

1-Nitro-1-(phenylthio)propene as a New Nitro Olefin Reagent for 3-Methylfuran Annulation and Its Application to the Synthesis of Some Furanoterpenoids

1-Nitro-1-(phenylthio)propene (9) was synthesized from (phenylthio)acetic acid (6) in five steps.This nitro olefin reacted with dimedone (1) with KF catalysis to yield dihydrofurans 10a and 10b, both of which were converted to 3-methylfuran 13 on NaIO4 ox