69697-53-6

Basic information

• Product Name: 4,4,5-Trimethyl-6,8-dioxa-3-thiabicyclo[3.2.1]octane
• Synonyms: 4,4,5-Trimethyl-6,8-dioxa-3-thiabicyclo[3.2.1]octane
• CAS NO: 69697-53-6
• Molecular Formula: C8H14O2S
• Molecular Weight: 174.26
• Mol File: 69697-53-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4,4,5-Trimethyl-6,8-dioxa-3-thiabicyclo[3.2.1]octane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,5-Trimethyl-6,8-dioxa-3-thiabicyclo[3.2.1]octane(69697-53-6)
• EPA Substance Registry System: 4,4,5-Trimethyl-6,8-dioxa-3-thiabicyclo[3.2.1]octane(69697-53-6)

Safety Data

• Hazardous Substances Data: 69697-53-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Canadian Journal of Chemistry, 61, p. 1487, 1983 DOI: 10.1139/v83-259

Upstream product

• 115-22-0 3-Hydroxy-3-methyl-2-butanone 
• 96-27-5 rac-3-sulfanylpropane-1,2-diol 

Relevant articles and documents

Heterobicycles sulfures derives de l'α-thioglycerol. Synthese d'alkyl-2,8-dioxa-6-thiabicyclooctanes

The synthesis of 2,8-dioxa-6-thiabicyclooctanes, substituted by alkyl or phenyl groups in positions 1, 4, or 7, is described.Four synthetic routes are compared: (i) action of sodium sulfide on 2,4-dichloro-1,3-dialkyldioxolanes; (ii) action of sodium sulfide on the ditosylates of 2,4-dihydroxyalkyl-1,3-dioxolanes; (iii) action of α-haloketones on α-thioglycerol; and (iv) action of α-hydroxyketones on α-thioglycerol.The structures of the dioxathiabicyclooctanes have been established by proton nmr (mass spectra have already been described) and chemically confirmed by desulfurization by Raney Nickel.