69813-81-6Relevant articles and documents
Efficient and selective aldehyde cyanosilylation catalyzed by Mg-Li bimetallic complex
Li, Jia,Yu, Ting,Luo, Man,Xiao, Qian,Yao, Weiwei,Xu, Li,Ma, Mengtao
, p. 83 - 86 (2018)
A NCN-pincer ligand-based Mg-Li bimetallic complex [NCN-MgBr2][Li(THF)4] 1 has been employed as an efficient catalyst for cyanosilylation of a wide range of aldehydes with trimethylsilyl cyanide (TMSCN) at room temperature in CDClsu
Cyanosilylation of carbonyl compounds with trimethylsilyl cyanide catalyzed by an yttrium-pillared silicotungstate dimer
Kikukawa, Yuji,Suzuki, Kosuke,Sugawa, Midori,Hirano, Tomohisa,Kamata, Keigo,Yamaguchi, Kazuya,Mizuno, Noritaka
supporting information; experimental part, p. 3686 - 3690 (2012/05/20)
An yttrium-pillared silicotungstate dimer (see picture) catalyzes the cyanosilylation of structurally diverse ketones and aldehydes with trimethylsilyl cyanide (TMSCN). The reactions proceed selectively and afford the corresponding cyanohydrin trimethylsi
