69824-92-6Relevant articles and documents
1,5-ADDITION OF DIALKYLCUPRATE REAGENTS TO ALKYLCYCLOPROPYL KETONES
Mioskowski, Charles,Manna, S.,Falck, J. R.
, p. 5521 - 5524 (1983)
Cyclopropyl ketones undergo 1,5-addition at the less substituted carbon using the complex reagent R2CuCNLi2*BF3.
Nickel (II) catalysed 1,4- addition reactions of functionalised organozinc reagents with enones
Yang, Danfeng Huang Yihua,Wang, Jin-Xian,Hu, Yulai
, p. 79 - 81 (2007/10/03)
An efficient catalytic 1,4 addition reaction of functionalised organozinc reagents with enones has been developed using a nickel complex as catalyst.
Neopentyl and neophyl groups: New nontransferable groups for organocopper and organozinc chemistry
Lutz, Christian,Jones, Philip,Knochel, Paul
, p. 312 - 316 (2007/10/03)
Neopentyl and Neophyl groups have been found to be excellent nontransferable groups for organozinc and organocopper chemistry. We have shown that mixed diorganozincs of the type FG-R-Zn(CH2CMe2R) can be used advantageously for the enantioselective addition to aldehydes. These mixed copper or zinc reagents are also found to be very efficient in the Michael addition to various activated alkenes.