6984-43-6

Basic information

• Product Name: (2S,3R,4S,5R,6R)-2,3,4,5-tetramethoxy-6-((trityloxy)methyl)tetrahydro-2H-pyran
• Synonyms: (2S,3R,4S,5R,6R)-2,3,4,5-tetramethoxy-6-((trityloxy)methyl)tetrahydro-2H-pyran
• CAS NO: 6984-43-6
• Molecular Weight: 478.585
• Mol File: 6984-43-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: (2S,3R,4S,5R,6R)-2,3,4,5-tetramethoxy-6-((trityloxy)methyl)tetrahydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4S,5R,6R)-2,3,4,5-tetramethoxy-6-((trityloxy)methyl)tetrahydro-2H-pyran(6984-43-6)
• EPA Substance Registry System: (2S,3R,4S,5R,6R)-2,3,4,5-tetramethoxy-6-((trityloxy)methyl)tetrahydro-2H-pyran(6984-43-6)

Safety Data

• Hazardous Substances Data: 6984-43-6(Hazardous Substances Data)

Upstream product

• 77-78-1 dimethyl sulfate 
• 18311-26-7 methyl 6-O-trityl-α-D-glucopyranoside 
• 74-88-4 methyl iodide 

Downstream Products

• 1256138-43-8 C₃₀H₄₂O₁₃ 
• 1441885-12-6 C₃₀H₄₂O₁₃ 
• 1256138-33-6 methyl (4,6-O-benzylidene-2-O-diazoacetyl-3-O-pivaloyl-β-D-glucopyranoside)-(1->6)-2,3,4-O-methyl-α-D-glucopyranoside 
• 1256138-40-5 C₃₀H₄₃BrO₁₃ 
• 1256138-30-3 C₃₀H₄₂O₁₃ 
• 1256138-27-8 methyl (4,6-O-benzylidene-2-O-diazoacetyl-3-O-pivaloyl-α-D-mannopyranoside)-(1->6)-2,3,4-O-methyl-α-D-glucopyranoside 
• 1256138-24-5 methyl (4,6-O-benzylidene-2-O-bromoacetyl-3-O-pivaloyl-α-D-mannopyranoside)-(1->6)-2,3,4-O-methyl-α-D-glucopyranoside 
• 1256138-21-2 C₃₀H₄₃BrO₁₃ 
• 213968-25-3 methyl 2,3,4-tri-O-methyl-6-O-methylsulfonyl-6-C-phenyl-α-D-glucopyranoside 
• 213968-27-5 1-O-acetyl-6-bromo-6-deoxy-2,3,4-tri-O-methyl-6-phenyl-α-D-glucopyranose 
• 213968-32-2 (8S,9S,10R)-8,9,10-Trimethoxy-7-[1-phenyl-meth-(Z)-ylidene]-1,4,6-trioxa-spiro[4.5]decane 
• 213968-31-1 6-bromo-1,6-dideoxy-1,1-ethylenedioxy-2,3,4-tri-O-methyl-6-phenyl-D-glucopyranose 
• 213968-30-0 (3R,4S,5S,6S)-6-(Bromo-phenyl-methyl)-3,4,5-trimethoxy-tetrahydro-pyran-2-one 
• 213968-26-4 methyl 6-bromo-6-deoxy-2,3,4-tri-O-methyl-6-phenyl-α-D-glucopyranoside 

Relevant articles and documents

Synthesis of novel carbohydrate based pyridinium ionic liquids and cytotoxicity of ionic liquids for mammalian cells

The large pool of naturally occurring carbohydrates with their diversity in chirality and structure led to the idea of a systematic investigation of carbohydrate based ILs. To this end, we investigated the influence of different ether groups, mainly methyl or ethyl ether, on the secondary OH groups as well as different configurations on physical properties such as melting point, thermostability and especially the influence on cell toxicity. For this investigation we chose α- and β-methyl-, β-allyl- and β-phenyl d-glucopyranose as well as four 1-deoxy-pentoses. In order to be able to classify the results, more ionic liquids with different structural motives were examined for cytotoxicity. Here, we present data that confirm the biocompatibility of such ILs consisting of naturally occurring molecules or their derivatives. The synthesized carbohydrate based ILs were tested for their suitability as additives in coatings for medical applications such as drug-eluting balloons.

Visible Light Enables Aerobic Iodine Catalyzed Glycosylation

A versatile protocol for light induced catalytic activation of thioglycosides using iodine as an inexpensive and readily available photocatalyst was developed. Oxygen serves as a green and cost-efficient terminal oxidant and irradiation is performed with a common household LED-bulb. The scope of this glycosylation protocol was investigated in the synthesis of O-glycosides with yields up to 95 %.

ANTI-CANCER AND SPLCE MODULATING COMPOUNDS AND METHODS

There are provided inter alia stable anti-cancer compounds and splice modulators and methods of synthesis and use thereof.