70004-62-5

Basic information

• Product Name: Cyclopropa[3,4]pentaleno[1,2-d][1,3]dioxole, 2a,2b,2c,5a,5b,5c-hexahydro-, (2a-alpha-,2b-alpha-,2c-bta-,5a-bta-,5b-alpha-,5c-alpha-)- (9CI)
• Synonyms: Cyclopropa[3,4]pentaleno[1,2-d][1,3]dioxole, 2a,2b,2c,5a,5b,5c-hexahydro-, (2a-alpha-,2b-alpha-,2c-bta-,5a-bta-,5b-alpha-,5c-alpha-)- (9CI)
• CAS NO: 70004-62-5
• Molecular Formula: C9H10O2
• Molecular Weight: 150.1745
• Mol File: 70004-62-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopropa[3,4]pentaleno[1,2-d][1,3]dioxole, 2a,2b,2c,5a,5b,5c-hexahydro-, (2a-alpha-,2b-alpha-,2c-bta-,5a-bta-,5b-alpha-,5c-alpha-)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropa[3,4]pentaleno[1,2-d][1,3]dioxole, 2a,2b,2c,5a,5b,5c-hexahydro-, (2a-alpha-,2b-alpha-,2c-bta-,5a-bta-,5b-alpha-,5c-alpha-)- (9CI)(70004-62-5)
• EPA Substance Registry System: Cyclopropa[3,4]pentaleno[1,2-d][1,3]dioxole, 2a,2b,2c,5a,5b,5c-hexahydro-, (2a-alpha-,2b-alpha-,2c-bta-,5a-bta-,5b-alpha-,5c-alpha-)- (9CI)(70004-62-5)

Safety Data

• Hazardous Substances Data: 70004-62-5(Hazardous Substances Data)

Upstream product

• 288-53-9 1,3-dioxole 
• 71-43-2 benzene 

Downstream Products

• 69956-67-8 4,7-diphenyl-(3ar,3bc,3cr',7ac',7bc,7cc,7dc,7ec)-3a,3b,3c,7a,7b,7c,7d,7e-octahydro-cyclopropa[3,4][1,3]dioxolo[4',5':5,6]pentaleno[1,2-d]pyridazine 

Relevant articles and documents

The Photo-cycloaddition of Enol Ethers to Benzene

The photo-reactions of benzene with ethyl vinyl ether, n-butyl vinyl ether, 1,1-dimethoxyethylene, 2,3-dihydropyran, 2,3-dihydrofuran, 2,3-dihydro-1,4-dioxin, and 1,3-dioxole are described.The meta-photo-cycloaddition of ethyl vinyl ether and n-butyl vinyl ether to benzene shows little selectivity, and regio- and stereo-isomers are isolated. ortho-Cycloaddition is observed from all systems but only with 2,3-dihydrofuran as addend are both stereoisomers of the adduct formed, and although the exo-isomer is very photolabile, the endo-product is essentially stable under its conditions of formation.The ortho-cycloaddition of 1,1-dimethoxyethylene to benzene provides the first step in a convenient synthesis of cyclo-octatrienone.Contrary to previous proposals there is little correlation between the stereochemistry of the ortho-cycloaddition and preferred orientation of the addends in the ground state.The relationship between the relative efficiency of the two addition modes and ionisation potential of the ethylene is discussed.