700336-73-8

Basic information

• Product Name: N-allyl-N-methyl-(4-methyl)benzamide
• Synonyms: N-allyl-N-methyl-(4-methyl)benzamide
• CAS NO: 700336-73-8
• Molecular Weight: 189.257
• Mol File: 700336-73-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-allyl-N-methyl-(4-methyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-allyl-N-methyl-(4-methyl)benzamide(700336-73-8)
• EPA Substance Registry System: N-allyl-N-methyl-(4-methyl)benzamide(700336-73-8)

Safety Data

• Hazardous Substances Data: 700336-73-8(Hazardous Substances Data)

Upstream product

• 18370-11-1 N-methyl-p-methylbenzamide 
• 106-95-6 allyl bromide 
• 917092-13-8 N-(2-bromo-allyl)-4,N-dimethyl-benzamide 
• 874-60-2 4-methyl-benzoyl chloride 

Relevant articles and documents

A Next-Generation Air-Stable Palladium(I) Dimer Enables Olefin Migration and Selective C?C Coupling in Air

We report a new air-stable PdI dimer, [Pd(μ-I)(PCy2tBu)]2, which triggers E-selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C?C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C?Br, C?OTf/OFs, and C?Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C?OTf.

A new highly chemoselective isomerization of allylamides

This work describes the first iridium-catalyzed isomerization of N-allylamides into enamides. This strategy allows the chemoselective preparation of (E)-N-(1-propenyl)-enamides and can be applied for the selective deprotection of N-allylamides.