70057-32-8

Basic information

• Product Name: 1-(trimethylsilylethynyl)-1,1-diphenyl-2,2,2-trimethyldisilane
• Synonyms: 1-(trimethylsilylethynyl)-1,1-diphenyl-2,2,2-trimethyldisilane
• CAS NO: 70057-32-8
• Molecular Weight: 352.699
• Mol File: 70057-32-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(trimethylsilylethynyl)-1,1-diphenyl-2,2,2-trimethyldisilane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(trimethylsilylethynyl)-1,1-diphenyl-2,2,2-trimethyldisilane(70057-32-8)
• EPA Substance Registry System: 1-(trimethylsilylethynyl)-1,1-diphenyl-2,2,2-trimethyldisilane(70057-32-8)

Safety Data

• Hazardous Substances Data: 70057-32-8(Hazardous Substances Data)

Upstream product

• 127348-36-1 chlorobis(trimethylsilyl)phenylsilane 
• 61211-96-9 1-chloro-1,1-diphenyl-2,2,2-trimethyldisilane 
• 1066-54-2 trimethylsilylacetylene 
• 132384-97-5 2-phenyl-2-(phenylethynyl)hexamethyltrisilane 

Downstream Products

• 70057-33-9 1,1,2,2-tetraphenyl-3,4-bis-1,2-disilacyclobutane 
• 77626-21-2 1,1-bis(trimethylsilyl)-2-(methoxydiphenylsilyl)ethene 
• 77607-88-6 C₂₁H₃₂OSi₃ 
• 77607-87-5 (E)-1,2-bis(trimethylsilyl)-1-(methoxydiphenylsilyl)ethene 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 77607-94-4 C₄₁H₆₀OSi₆ 
• 77607-95-5 4-(Bis-trimethylsilanyl-vinylidene)-2,2,5,5-tetraphenyl-3,3-bis-trimethylsilanyl-[1,2,5]thiadisilolane 
• 77607-93-3 C₄₁H₆₀OSi₆ 
• 70057-36-2 2,2,5,5-tetraphenyl-3,4-bis-1-oxa-2,5-disilacyclopentane 
• 70057-35-1 2,2,5,5-tetraphenyl-3-bis(trimethylsilyl)ethenylidene-4,4-bis(trimethylsilyl)-1-oxa-2,5-disilacyclopentane 
• 70057-34-0 1,1,2,2-tetraphenyl-3--4,4-bis(trimethylsilyl)-1,2-disilacyclobutane 

Relevant articles and documents

Silicon-carbon unsaturated compounds XXVII. Nickel-catalyzed reactions of 2-phenyl- and 2-(o-tolyl)-2-(phenylethynyl)hexamethyltrisilane

The nickel-catalyzed reactions of 2-phenyl- and 2-(o-tolyl)-2-(phenylethynyl)hexamethyltrisilane (I and II) with phenyl(trimethylsilyl)acetylene at 180 deg C have been examined.The reaction of I with phenyl(trimethylsilyl)acetylene in the presence of tetrakis(triethylphosphine)nickel(0) gave 1,3-diphenyl-2--1,4-bis(trimethylsilyl)-1-silacyclobut-3-ene and 1,4,4-trimethyl-1,3,6-triphenyl-2,5-bis(trimethylsilyl)-1,4-disilacyclohexa-2,5-diene.Similar reaction of II produced 3-phenyl-2--1-(o-tolyl)-1,4-bis(trimethylsilyl)-1-silacyclobut-3-ene and 4,4,5-trimethyl-2,6-diphenyl-1,3-bis(trimethylsilyl)-1-(o-tolyl)-1,4-disilacyclohexa-2,5-diene.The results of the reactions of I and II in the presence of a catalytic amount of the nickel(0) complex in the absence of phenyl(trimethylsilyl)acetylene are also described.