70083-69-1

Basic information

• Product Name: Tetramethylammonium Bis<α,α-bis(trifluoromethyl)-benzenemethanolato(2-)-C²,O>phenylsilicate
• Synonyms: Tetramethylammonium Bis<α,α-bis(trifluoromethyl)-benzenemethanolato(2-)-C²,O>phenylsilicate
• CAS NO: 70083-69-1
• Molecular Weight: 663.578
• Mol File: 70083-69-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Tetramethylammonium Bis<α,α-bis(trifluoromethyl)-benzenemethanolato(2-)-C²,O>phenylsilicate(CAS DataBase Reference)
• NIST Chemistry Reference: Tetramethylammonium Bis<α,α-bis(trifluoromethyl)-benzenemethanolato(2-)-C²,O>phenylsilicate(70083-69-1)
• EPA Substance Registry System: Tetramethylammonium Bis<α,α-bis(trifluoromethyl)-benzenemethanolato(2-)-C²,O>phenylsilicate(70083-69-1)

Safety Data

• Hazardous Substances Data: 70083-69-1(Hazardous Substances Data)

Upstream product

• 98-13-5 Phenyltrichlorosilane 
• 591-51-5 phenyllithium 
• 70091-69-9 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole> 
• 70083-67-9 (TB-5-11)-bis-(1,1,1,3,3,3-hexafluoro-2-phenyl-propan-2-olato^(2-)-C^2',O)-phenyl-silicate^(1-); lithium salt 

Downstream Products

• 97878-08-5 tetrabutylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O><3,5-bis(trifluoromethyl)phenyl>silicate (1-) 
• 97878-02-9 tetrabutylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>(pentafluorophenyl)silicate(1-) 
• 97878-01-8 tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>(pentafluorophenyl)silicate(1-) 
• 97878-07-4 tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato (2-)-C²,O><3-(trifluoromethyl)phenyl>silicate(1-) 
• 97878-05-2 tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato (2-)-C²,O>(4-methoxyphenyl)silicate(1-) 
• 97878-09-6 lithium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C²,O>-phenoxysilicate (1-) 
• 108-86-1 bromobenzene 
• 70091-69-9 C₁₈H₈F₁₂O₂Si 
• 71-43-2 benzene 

Relevant articles and documents

Directed Dilithiation of Hexafluorocumyl Alcohol - Formation of a Reagent for the Facile Introduction of a Stabilizing Bidentate Ligand in Compounds of Hypervalent Sulfur (10-S-4), Phosphorus (10-P-5), Silicon (10-Si-5), and Iodine (10-I-3)

The reaction of 1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanol (RFOH) with either sec-butyllithium or n-bulyllithium/N,N,N'N'-tetramethylethylenediamine (TMEDA) provides 3, a reagent for the facile introduction of a bidentate ligand which is partic