701-13-3

Basic information

• Product Name: PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER
• Synonyms: 1-PYRROLIDINECARBODITHIOIC ACID ALLYL ESTER;ALLYL PYRROLIDINODITHIOCARBAMATE;ALLYL 1-PYRROLIDINECARBODITHIOATE;PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER;PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER 95+%;N-Pyrrolizinodithiocarbamic acid allyl ester;Pyrrolidinodithiocarbamic Acid Allyl Ester Allyl Pyrrolidinodithiocarbamate 1-Pyrrolidinecarbodithioic Acid Allyl Ester
• CAS NO: 701-13-3
• Molecular Formula: C₈H₁₃NS₂
• Molecular Weight: 202.34
• Product Categories: Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry
• Mol File: 701-13-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 255.1°C at 760 mmHg
• Flash Point: 108.1°C
• Appearance: /
• Density: 1.14
• Vapor Pressure: 0.0166mmHg at 25°C
• Refractive Index: 1.6130-1.6160
• Storage Temp.: Refrigerator
• CAS DataBase Reference: PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER(701-13-3)
• EPA Substance Registry System: PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER(701-13-3)

Safety Data

• Hazardous Substances Data: 701-13-3(Hazardous Substances Data)

Usage

Uses

Allyl 1-Pyrrolidinecarbodithioate is an intermediate for the synthesis of dithiocarbamate series.

InChI:InChI=1/C8H13NS2/c1-2-7-11-8(10)9-5-3-4-6-9/h2H,1,3-7H2

Upstream product

• 123-75-1 pyrrolidine 
• 75-15-0 carbon disulfide 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 86826-34-8 Pyrrolidine-1-carbodithioic acid 1-phenethyl-allyl ester 
• 86826-37-1 Pyrrolidine-1-carbodithioic acid (E)-5-phenyl-pent-2-enyl ester 
• 86826-40-6 Pyrrolidine-1-carbodithioic acid (E)-5-phenyl-1-trimethylsilanylmethyl-pent-2-enyl ester 
• 135924-48-0 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-hept-2-enyl ester 
• 135947-70-5 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-5-methyl-hex-2-enyl ester 
• 135924-49-1 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-6-methyl-hept-2-enyl ester 
• 135924-50-4 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-non-2-enyl ester 
• 135924-53-7 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-4-phenyl-but-2-enyl ester 
• 135924-54-8 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-5-phenyl-pent-2-enyl ester 
• 135924-55-9 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-6-phenyl-hex-2-enyl ester 
• 135924-51-5 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-11-[1,3]dioxolan-2-yl-undec-2-enyl ester 
• 135924-52-6 Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-11-[1,3]dithiolan-2-yl-undec-2-enyl ester 

Relevant articles and documents

An efficient synthesis of dithiocarbamates under ultrasound irradiation in water

Multicomponent reactions with ultrasonic activation have been used as a simple, rapid, atom economic, and green method for the synthesis of dithiocarbamate derivatives in water. The one-pot, three-component condensation of primary and secondary amines with carbon disulfide and unsaturated carbonyl compounds or alkyl halides under ultrasonic irradiation was developed as a green and fast protocol for the rapid high-yielding preparation of dithio-carbamates in water.

Straightforward and highly efficient catalyst-free one-pot synthesis of dithiocarbamates under solvent-free conditions

A highly efficient and simple synthesis of dithiocarbamates is possible based on the one-pot reaction of amines, CS2, and alkyl halides without using a catalyst under solvent-free conditions. The mild reaction conditions, high yields, and broad scope of the reaction illustrate the good synthetic utility of this method. The reaction is a highly atom-economic process for production of S-alkyl thiocarbamates and successfully can be used in high quantities in the pharmaceutical or agrochemical industries.