701-94-0

Basic information

• Product Name: 2-BROMO-4-(CHLOROMETHYL)-1-METHOXYBENZENE
• Synonyms: 1-broMo-4-(chloroMethyl)-2-Methoxybenzene
• CAS NO: 701-94-0
• Molecular Formula: C₈H₈BrClO
• Molecular Weight: 235.51
• Mol File: 701-94-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 287.1°C at 760 mmHg
• Flash Point: 127.4°C
• Appearance: /
• Density: 1.497g/cm³
• Vapor Pressure: 0.00438mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: 2-BROMO-4-(CHLOROMETHYL)-1-METHOXYBENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BROMO-4-(CHLOROMETHYL)-1-METHOXYBENZENE(701-94-0)
• EPA Substance Registry System: 2-BROMO-4-(CHLOROMETHYL)-1-METHOXYBENZENE(701-94-0)

Safety Data

• Hazardous Substances Data: 701-94-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H8BrClO/c1-11-8-3-2-6(5-10)4-7(8)9/h2-4H,5H2,1H3

Upstream product

• 38493-59-3 (3-bromo-4-methoxy-phenyl)-methanol 
• 123-11-5 4-methoxy-benzaldehyde 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 772-59-8 (3-bromo-4-methoxyphenyl)-acetonitrile 
• 78978-75-3 N-[1-(3-Bromo-4-methoxy-benzylsulfanyl)-1-methoxy-meth-(Z)-ylidene]-benzamide 
• 121593-85-9 N¹-(3-bromo-4-methoxybenzyl)-N³-methyl-6-methoxyuracil 
• 121593-80-4 1-(3-Bromo-4-methoxy-benzyl)-6-(2-hydroxy-ethylamino)-3-methyl-1H-pyrimidine-2,4-dione 
• 774-81-2 (3-bromo-4-methoxy-phenyl)-acetic acid 
• 17054-19-2 (3-bromo-4-methoxy-phenyl)-acetic acid-(4-benzyloxy-3-methoxy-phenethylamide) 
• 179260-94-7 4-[(4-(2-pyrimidinyl)-piperazinyl)methyl]-2-bromoanisole 
• 500113-97-3 C₁₉H₁₉Br₂N₃O₂S 
• 500113-98-4 C₂₄H₂₁Br₂N₃O₂S 
• 354550-14-4 5-(3-bromo-4-methoxybenzyl)mercapto-2-(4-ethoxybenzyl)-1,3,4-thiadiazole 
• 500114-00-1 3-[(3-bromo-4-methoxybenzyl)sulfanyl]-4-methyl-5-(4-ethoxybenzyl)-4H-1,2,4-triazole 
• 500114-02-3 C₂₁H₂₄BrN₃O₂S 
• 500114-04-5 C₂₂H₂₆BrN₃O₂S 
• 500114-03-4 C₂₂H₂₆BrN₃O₂S 

Relevant articles and documents

RAFT polymerization of bromotyramine-based 4-acryloyl-1,2,3-triazole: A functional monomer and polymer family through click chemistry

Four new functional acryloyl-triazole monomers derived from bromotyramine were successfully synthesized. These monomers were prepared in an efficient way from organic azides and propargyl acrylate via a copper catalyzed 1,3-dipolar cycloaddition. Polymers containing bromotyramine as a pendant group were obtained via reversible addition-fragmentation chain transfer (RAFT) polymerization. The influence of the chain transfer agent (CTA), solvent, temperature and the length of the linker between the triazole and bromotyramine groups on the polymerization kinetics was studied. It was found that triazoles containing acrylate monomers are characterized by fast polymerization and polymers with controlled molar masses (20 000 g mol-1) and low dispersities (DM 1.5) can be prepared. Glass transition temperatures of these acrylic polymers ranged from 48 °C to 20 °C by controlling the length of the linker between the bromotyramine side groups and the backbone.