70132-76-2

Basic information

• Product Name: 3-phenyl-1,2-benzothiazole
• CAS NO: 70132-76-2
• Molecular Formula: C₁₃H₉NS
• Molecular Weight: 211.2823
• Mol File: 70132-76-2.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 293.7°C at 760 mmHg
• Flash Point: 122.8°C
• Density: 1.231g/cm³
• Vapor Pressure: 0.00298mmHg at 25°C
• Refractive Index: 1.684
• CAS DataBase Reference: 3-phenyl-1,2-benzothiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenyl-1,2-benzothiazole(70132-76-2)
• EPA Substance Registry System: 3-phenyl-1,2-benzothiazole(70132-76-2)

Safety Data

• Hazardous Substances Data: 70132-76-2(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 344262-41-5 C₂₄H₂₃NO₂S 
• 5162-03-8 (2-chlorophenyl)(phenyl)methanone 
• 117136-72-8 (2-Methylsulfanyl-phenyl)-phenyl-methanone oxime 
• 344244-72-0 C₂₃H₂₁NO₂S 
• 82070-32-4 C₂₀H₂₄N₂OS₂ 
• 345318-10-7 C₂₀H₂₄N₂OS₂ 
• 174532-69-5 2-mercaptobenzhydrylidenamine 
• 352427-10-2 tert-Butyl [({phenyl[2-(phenylsulfanyl)phenyl]methylidene}amino)oxy]peracetate 
• 52252-61-6 phenyl[(2-phenylsulfanyl)phenyl]methanone 
• 352427-06-6 [({Phenyl[2-(phenylsulfanyl)phenyl]methylidene}amino)oxy]acetic acid 
• 108-98-5 thiophenol 
• 100-47-0 benzonitrile 
• 82243-31-0 C-(2-Isopropylsulfanyl-phenyl)-C-phenyl-methyleneamine 

Downstream Products

• 80816-78-0 (6R,7R)-6,7-Dimethyl-9-phenyl-6,7-dihydro-5-thia-8-aza-benzocycloheptene 
• 78134-70-0 3-Ethoxy-5-phenyl-2,3-dihydro-1,4-benzothiazepine 
• 38210-55-8 2-(Diethylamino)-3-phenylbenzothiophene 
• 84538-83-0 4-(Diethylamino)-3-methyl-1-phenylisoquinoline 
• 84538-80-7 1-(Diethylamino)-7-methyl-5-phenyl-3,4-benzo-2,6-thiazabicyclo<3.2.0>hepta-3,6-diene 
• 57642-62-3 2-methyl-3-phenylbenzothiophen 
• 84538-78-3 3-Ethoxy-4-methyl-1-phenylisoquinoline 
• 84538-74-9 7-Ethoxy-1-methyl-5-phenyl-3,4-benzo-2,6-thiazabicyclo<3.2.0>hepta-3,6-diene 
• 14315-12-9 3-phenyl-1-benzothiophene 
• 84538-77-2 3-ethoxy-1-phenyl-isoquinoline 
• 84538-88-5 5-Phenyl-3,4-benzo-2,6-thiazabicyclo<3.2.0>hept-3-en-7-one 
• 84538-73-8 7-Ethoxy-5-phenyl-3,4-benzo-2,6-thiazabicyclo<3.2.0>hepta-3,6-diene 
• 84538-85-2 Ethyl 2,3-dihydro-3-amino-3-phenylbenzothiophenyl-2-carboxylate 
• 80824-65-3 [2-(2-Amino-1,1,2-trimethyl-propylsulfanyl)-phenyl]-phenyl-methanone 

Relevant articles and documents

Synthesis of Isothiazoles and Isoselenazoles through Rhodium-Catalyzed Oxidative Annulation with Elemental Sulfur and Selenium

A rhodium-catalyzed oxidative annulation of benzimidates with elemental sulfur for the direct construction of isothiazole rings is reported. The proposed reaction mechanism involving Rh(I)/Rh(III) redox is supported by a stoichiometric reaction of metallacycle species as well as DFT calculations. This method is also applicable to selenium cyclization to produce isoselenazole derivatives. The alkoxy substituent at C3 can be used for further functionalization of the azole core.

IRIDIUM COMPLEX AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME

The present invention discloses an iridium complex represented by the following formula (1) and an organic electroluminescence device using the iridium complex as a phosphorescent dopant material. The phosphorescent dopant material may lower a driving voltage and power consumption and increase a current efficiency and half-life of the organic electroluminescence device. The same definition as described in the present invention.

Preparation of Thioanisole Biscarbanion and C-H Lithiation/Annulation Reactions for the Access of Five-Membered Heterocycles

The synthesis, isolation, and X-ray structure of a thioanisole-based trilithium complex are reported. On the basis of the double-lithiation strategy, two novel synthetic methodologies have been developed under mild reaction conditions (room temperature): (1) reactions of lithiated thioanisoles with nitriles give benzoisothiazoles via a [3 + 2]-type of approach with two new bond formations and (2) formation of benzothiophenes from thioanisoles and amides through a [4 + 1] pattern forming 4 new chemical bonds.