70144-57-9

Basic information

• Product Name: methyl 4,6-O-benzylidene-3-O-methyl-β-D-glucopyranoside
• Synonyms: methyl 4,6-O-benzylidene-3-O-methyl-β-D-glucopyranoside
• CAS NO: 70144-57-9
• Molecular Weight: 296.32
• Mol File: 70144-57-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-3-O-methyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-3-O-methyl-β-D-glucopyranoside(70144-57-9)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-3-O-methyl-β-D-glucopyranoside(70144-57-9)

Safety Data

• Hazardous Substances Data: 70144-57-9(Hazardous Substances Data)

Upstream product

• 14982-01-5 methyl 3-O-methyl-β-D-glucopyranoside 
• 81825-61-8 methyl 2-O-acetyl-4,6-O-benzylidene-3-O-methyl-α-D-galactopyranoside 
• 30694-94-1 2,4,6-tri-O-acetate-3-O-methyl-α-D-glucopyranosylbromide 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 4163-64-8 1,2,4,6-tetra-O-acetate-2-O-methyl-β-D-glucopyranoside 
• 71117-37-8 (2R,4aR,6R,7R,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 74-88-4 methyl iodide 
• 333-27-7 methyl trifluoromethanesulfonate 
• 120408-72-2 Methyl 2,3-anhydro-4,6-O-(phenylmethylene)-β-D-allopyranoside 
• 146-72-5 3-O-methyl-D-glucose 

Downstream Products

• 1199797-32-4 O⁴,O⁶-(R)-benzylidene-O¹,O³-dimethyl-β-D-arabino-[2]hexosul-1,5-ose 
• 1199797-24-4 C₁₅H₁₈O₆ 
• 81825-63-0 methyl 2-O-benzyl-4,6-O-benzylidene-3-O-methyl-α-D-galactopyranoside 
• 120200-48-8 methyl 4,6-O-benzylidene-2,3-di-O-methyl-β-D-glucopyranoside 
• 7045-54-7 methyl 4,6-O-benzylidene-2-deoxy-3-O-methyl-2C-p-methylsulfonyl-β-D-glucopyranoside 
• 14897-55-3 methyl-[O²-benzyl-O⁴,O⁶-((R)-benzylidene)-O³-methyl-β-D-glucopyranoside] 

Relevant articles and documents

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Versatile syntheses of C2-linked and C2-symmetric carbohydrate-based imidazol(in)ium salts from functionalised amino-carbohydrate derivatives are reported. The novel NHCs were ligated to [Rh(COD)Cl]2 and evaluated in Rh-catalysed asymmetric hydrosilylation of ketones with good yields and promising enantioselectivities.

Synthesis of monodeoxy and mono-O-methyl congeners of methyl β-d-mannopyranosyl-(1→2)-β-d-mannopyranoside for epitope mapping of anti-Candida albicans antibodies

A panel of six complementary monodeoxy and mono-O-methyl congeners of methyl β-d-mannopyranosyl-(1→2)-β-d-mannopyranoside (1) were synthesized by stereoselective glycosylation of monodeoxy and mono-O-methyl monosaccharide acceptors with a 2-O-acetyl-gluco

ALKYLATION OF METHYL 4,6-O-BENZYLIDENE-α-D-GALACTOPYRANOSIDE

The partial alkylation of methyl 4,6-benzylidene-α-D-galactopyranoside in dimethylformamide and dimethyl sulfoxide in the presence of barium oxide and hydroxide is described.It has been shown that methylation and benzylation lead predominantly to the 3-al