702-90-9

Basic information

• Product Name: cyclopropane-1,1,2-tricarboxylic acid
• CAS NO: 702-90-9
• Molecular Formula: C₆H₆O₆
• Molecular Weight: 174.1082
• Mol File: 702-90-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 397.2°C at 760 mmHg
• Flash Point: 208.2°C
• Density: 1.969g/cm³
• Vapor Pressure: 2.04E-07mmHg at 25°C
• Refractive Index: 1.645
• CAS DataBase Reference: cyclopropane-1,1,2-tricarboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: cyclopropane-1,1,2-tricarboxylic acid(702-90-9)
• EPA Substance Registry System: cyclopropane-1,1,2-tricarboxylic acid(702-90-9)

Safety Data

• Hazardous Substances Data: 702-90-9(Hazardous Substances Data)

Upstream product

• 839-39-4 cyclopropane-1,1,2-tricarboxylic acid triethyl ester 
• 33626-79-8 1-acetyl-2-vinylcyclopropanecarboxylic acid ethyl ester 
• 65590-89-8 ethyl 1-cyano-2-vinylcyclopropane-1-carboxylate 
• 685-87-0 Diethyl 2-bromomalonate 
• 107-13-1 acrylonitrile 
• 140-88-5 ethyl acrylate 
• 75911-83-0 1-ethyl 2-methyl 1-(2-methoxyacetyl)cyclopropane-1,2-dicarboxylate 
• 3674-13-3 2,3-dibromopropionic acid ethyl ester 
• 105-53-3 diethyl malonate 
• 144829-35-6 Dimethyl 2-methoxycarbonyl-3-methylenesuccinate 
• 876488-15-2 3-bromo-propane-1,1,2-tricarboxylic acid trimethyl ester 
• 67-56-1 methanol 
• 22650-26-6 trimethyl cyclopropane-1,1,2-tricarboxylate 
• 7664-93-9 sulfuric acid 

Downstream Products

• 5617-74-3 3-oxabicyclo[3.1.0]hexane-2,4-dione 
• 305377-31-5 1-trifluoromethyl-cis-1,2-cyclopropanedicarboxylic acid 
• 53358-22-8 (Z)-γ-methylglutaconic acid 
• 5621-44-3 dimethyl 2-methylenepentanedioate 
• 114644-54-1 cis-1-hydroxymethylcyclopropane-1,2-dicarboxylic acid 
• 114644-57-4 dimethyl cis-1-(p-tolylsulphonyloxymethyl)cyclopropane-1,2-dicarboxylate 

Relevant articles and documents

Synthesis, thermal, mass and ab initio analyses of cyclopropane-1,1,2- tricarboxylic acid

The preparation of cyclopropane-1,1,2-tricarboxylic acid from cyanoacetic acid and 2,3-dibropropionic acid has been done in one-step procedure in alkaline medium. The compound has been characterized, by nuclear magnetic resonance, mass spectrometry, and t

CYCLOPROPANE-1,1 prime -INDENES.

The relative concentrations of stereoisomers in product mixtures were determined as a function of time by using a combination of analytical techniques: vapor phase chromatography, polarimetry, NMR spectroscopy, and NMR spectroscopy in the presence of an optically active lanthanide shift reagent. The stereochemical reaction kinetics reveal that the Smith mechanism is not a plausible model for one-center epimerization; two trimethylenes, produced through two distinct cyclopropane C-C bond cleavages, are implicated, since all three possible one-center epimerizations are seen.