702-92-1Relevant articles and documents
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Patel,D.J. et al.
, p. 3218 - 3223 (1963)
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Synthesis of racemic cis-1-alkyl- and 1-aryl-2-aminocyclopropanecarboxylic esters
Mangelinckx, Sven,De Kimpe, Norbert
, p. 1771 - 1774 (2007/10/03)
The title cyclic β-amino esters were synthesized stereo- and regioselectively. Starting from the corresponding 1-aryl- and 1-alkylcyclopropane-1,2-dicarboxylates, selective monosaponification and subsequent Curtius reaction leads to certain cis-1-alkyl- and 1-aryl-2-aminocyclopropanecarboxylic esters. These β-aminocyclopropanecarboxylate derivatives (β-ACCs) can be seen as useful building blocks for β-peptides.
Hinweise auf einen Fragmentierungsmechanismus bei Coenzym-B12-abhaengigen Umlagerungen des Kohlenstoffgeruests
Beatrix, Birgitta,Zelder, Oskar,Kroll, Friedrich K.,Oerlygsson, Gissur,Golding, Bernard T.,Buckel, Wolfgang
, p. 2573 - 2576 (2007/10/03)
Keywords: Coenzym B12, Enzymkatalyse, Umlagerungen
1,5-BIS(TRIMETHYLSILOXY)-1,5-DIMETHOXY-1, 4-PENTADIENES PRECURSORS FOR THE SYNTHESIS OF CYCLOPROPANES AND CYCLOBUTANES
Wallace, I. H. M.,Chan, T. H.
, p. 847 - 854 (2007/10/02)
1,5-Bis(trimethylsiloxy)-1,5-dimethoxy-1,4-pentadienes (7) can be prepared in good yield by silylation of the dianions of dimethyl glutarates (8).On treatment with titanium tetrachloride, 7 cyclise stereoselectively to dimethyl trans-cyclopropane-1,2-dica