70207-45-3

Basic information

• Product Name: Phosphoric acid, diethyl (4-nitrophenyl)methyl ester
• CAS NO: 70207-45-3
• Molecular Formula: C11H16NO6P
• Molecular Weight: 289.225
• Mol File: 70207-45-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphoric acid, diethyl (4-nitrophenyl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric acid, diethyl (4-nitrophenyl)methyl ester(70207-45-3)
• EPA Substance Registry System: Phosphoric acid, diethyl (4-nitrophenyl)methyl ester(70207-45-3)

Safety Data

• Hazardous Substances Data: 70207-45-3(Hazardous Substances Data)

Upstream product

• 619-73-8 4-nitrobenzyl chloride 
• 814-49-3 diethyl chlorophosphate 

Downstream Products

• 70207-47-5 3,6-bis(4-nitrostyryl)-9-ethyl carbazole 
• 18648-70-9 1,1-diphenyl-2-(4-nitrophenyl)ethene 
• 736-31-2 trans-4,4'-dinitrostilbene 
• 1075218-62-0 (E)-4-iodostyrylnitrobenzene 
• 1075218-63-1 4-[2-(4-iodo-phenyl)-vinyl]-phenylamine 
• 1075218-61-9 N-methyl-{4-[2-(4-amino-phenyl)-vinyl]-phenyl}-amine 
• 7314-06-9 (E)-4,4'-diaminostilbene 
• 1075218-64-2 4-[2-(4-tributylstannanylphenyl)vinyl]phenylamine 
• 22525-43-5 trans-4′-(N,N′-dimethylamino)-4-aminostilbene 
• 2844-15-7 N,N-dimethyl-4-[(E)-2-(4-nitrophenyl)vinyl]aniline 
• 3145-86-6 4-nitrobenzyl iodide 
• 1817-77-2 4-benzyl-1-nitrobenzene 

Relevant articles and documents

Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids

(Chemical Equation Presented) Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids was investigated. Optimum conditions employed the simple catalytic system of palladium(II) acetate (1 mol %) and triphenylphosphine (4 mol %) with either potassium phosphate or potassium carbonate as the base and toluene as the solvent at 90°C. Using the developed conditions, a series of structurally diverse diarylmethanes were prepared.

Synthesis of diarylmethanes through palladium-catalyzed coupling of benzylic phosphates with arylsilanes

An efficient approach to the benzylation of arenes has been developed. The reactions described provide straightforward access to diarylmethanes through Pd-catalyzed coupling of benzylic phosphates with arylsilanes in good to excellent yields. The reaction tolerates a wide range of functionalities such as halide, alkoxyl, and nitro groups.