70218-44-9Relevant articles and documents
Stereospecific substitution of allylic alcohols to give optically active primary allylic amines: Unique reactivity of a (P,alkene)Ir complex modulated by iodide
Roggen, Markus,Carreira, Erick M.
supporting information; experimental part, p. 11917 - 11919 (2010/11/04)
A stereospecific allylic amination of unactivated secondary (2°)-allylic alcohols is reported. The primary (1°)-allylic amine can be isolated directly or protected in situ. Spectroscopic studies have shed light on the structure of the catalytically active Ir?(P,olefin)2I complex.