70223-96-0

Basic information

• Product Name: α-Acetobrommaltose
• CAS NO: 70223-96-0
• Molecular Weight: 699.458
• Mol File: 70223-96-0.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: α-Acetobrommaltose(CAS DataBase Reference)
• NIST Chemistry Reference: α-Acetobrommaltose(70223-96-0)
• EPA Substance Registry System: α-Acetobrommaltose(70223-96-0)

Safety Data

• Hazardous Substances Data: 70223-96-0(Hazardous Substances Data)

Upstream product

• 3616-19-1 1,2,3,6,2',3',4',6'-octa-O-acetylmaltose 
• 3616-19-1 Octa-O-acetyl-β-D-maltose 
• 18464-08-9 2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-D-glucopyranose 
• 6920-00-9 D-maltose octaacetate 
• 22352-19-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl-(1->4)-2,3,6-tri-O-acetyl-β-D-glucopyranosyl acetate 
• 18464-08-9 2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl-(1->4)-2,3,6-tri-O-acetyl-β-D-glucopyranose 
• 20764-63-0 β-cellobioseoctaacetate 
• 69-79-4 D-maltose 

Downstream Products

• 87956-88-5 (4-nitro-phenyl)-[O²,O³,O⁶-triacetyl-O⁴-(tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranoside] 
• 51450-24-9 hexa-O-acetyl-D-maltal 
• 33012-49-6 1-azido-1-deoxy-4-O-(2',3',4',6'-tetra-O-acetyl-α-D-glucopyranosyl)-2,3,6-tri-O-acetyl-β-D-glucose 
• 15896-49-8 maltose-1-phosphate 
• 96022-70-7 2-O-Benzyl-3-O-tetradecyl-1-O-<2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranosyl>-sn-glycerin 
• 96022-72-9 2-O-Benzyl-3-O-octadecyl-1-O-<2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranosyl>-rac-glycerin 
• 744-05-8 methyl beta-D-maltoside 
• 77110-60-2 Pentachlorophenyl 2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranoside 
• 141243-29-0 3,5-Dimethoxy-4-4)-2,3,6-tri-O-acetyl-β-D-glucopyranosyloxy>acetophenone 
• 130184-91-7 3-methoxy-4-4)-2,3,6-tri-O-acetyl-β-D-glucopyranosyloxy>acetophenone 
• 53669-33-3 4-acetoxy-3,5-dimethoxybenzaldehyde 
• 3616-19-1 1,2,3,6,2',3',4',6'-octa-O-acetylmaltose 
• 141243-30-3 3,5-Dimethoxy-4-4)-2,3,6-tri-O-acetyl-β-D-glucopyranosyloxy>benzaldehyde 
• 121401-76-1 7,2'',3'',6'',2''',3''',4''',6'''-octa-O-acetyl-2,3,4',5',6',7'-hexa-O-benzylvalidamycin E 

Relevant articles and documents

A convenient synthesis of peracetylated glycosyl halides using bismuth(III) halides as catalysts

A new halogenation procedure for peracetylated glycopyranosides is reported, using bismuth(III) halides and halogenosilanes under very mild conditions.

Halogenation and anomerization of glycopyranoside by TESH/bromine and BHQ/bromine

Treatment of peracetylated glycosides and β-isopropyl glycosides with halogen in the presence of TESH and BHQ has been found to result in the halogenation and the anomerization, respectively. Peracetylatedglycosides treaded with I2/TESH or Br2/TESH leading tothe formation of corresponding glycosyl halides, and b-isopropyl glycosidesreacted with Br2/BHQ resulting in the formation of a-glycosides. The anomerizationof glycosidic bond was considered to be catalyzed by in situ formation of hydrogenbromide from the mixing of Br2/BHQ.

Chemical synthesis of 5’-β-glycoconjugates of vitamin B6

Various 5’-β-saccharides of pyridoxine, namely the mannoside, galactoside, arabinoside, maltoside, cellobioside and glucuronide, were synthesized chemically according to KOENIGS-KNORR conditions using α4,3-O-isopropylidene pyridoxine and the respective acetobromo glycosyl donors with AgOTf (3.0 eq.) and NIS (3.0 eq.) as promoters at 0 °C. Furthermore, 5’-β-[13C6]-labeled pyridoxine glucoside (PNG) was prepared starting from [13C6]-glucose and pyridoxine. Additionally, two strategies were examined for the synthesis of 5’-β-pyridoxal glucoside (PLG).