70255-36-6

Basic information

• Product Name: Butanedioic acid, (phenylsulfonyl)-, 4-[(3E)-5-(acetyloxy)-3-pentenyl] 1-methyl ester
• CAS NO: 70255-36-6
• Molecular Formula: C18H22O8S
• Molecular Weight: 398.434
• Mol File: 70255-36-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Butanedioic acid, (phenylsulfonyl)-, 4-[(3E)-5-(acetyloxy)-3-pentenyl] 1-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanedioic acid, (phenylsulfonyl)-, 4-[(3E)-5-(acetyloxy)-3-pentenyl] 1-methyl ester(70255-36-6)
• EPA Substance Registry System: Butanedioic acid, (phenylsulfonyl)-, 4-[(3E)-5-(acetyloxy)-3-pentenyl] 1-methyl ester(70255-36-6)

Safety Data

• Hazardous Substances Data: 70255-36-6(Hazardous Substances Data)

Upstream product

• 34097-60-4 methyl benzenesulfonylacetate 
• 94844-33-4 ethyl (E)-5-((tert-butyldimethylsilyl)oxy)pent-2-enoate 
• 112906-38-4 (E)-5-((tert-butyldimethylsilyl)oxy)pent-2-en-1-yl acetate 
• 86462-75-1 (E)-5-(tert-butyldimethylsilanyloxy)pent-2-en-1-ol 
• 70255-35-5 (E)-5-hydroxypent-2-en-1-yl acetate 
• 60729-65-9 sodim salt of methyl benzenesulfonylacetate 
• 73843-00-2 (E)-1-acetoxy-2-penten-5-yl bromoacetate 
• 90449-01-7 pent-4-en-1-yl 2-bromoacetate 
• 821-09-0 n-Pent-4-enyl alcohol 
• 844494-17-3 1'-penten-5'-yl 3-benzenesulfonyl-3-carbomethoxypropanoate 
• 64-19-7 acetic acid 
• 598-21-0 2-Bromoacetyl bromide 

Downstream Products

• 70255-37-7 (Z)-4-Benzenesulfonyl-2-oxo-2,3,4,5,8,9-hexahydro-oxonine-4-carboxylic acid methyl ester 
• 70575-33-6 (E)-4-Benzenesulfonyl-2-oxo-2,3,4,5,8,9-hexahydro-oxonine-4-carboxylic acid methyl ester 
• 70255-38-8 3-benzenesulfonyl-3-carbomethoxy-8-hydroxy-octanoate lactone 

Relevant articles and documents

Hydrocarbon oxidation vs C-C bond-forming approaches for efficient syntheses of oxygenated molecules

(Chemical Equation Presented) A hydrocarbon oxidation approach has been applied to the construction of several linear (E)-allylic alcohols that have served as intermediates in the synthesis of natural products and natural product-like molecules. In the original syntheses, these intermediates were constructed using a standard Wittig-type olefination approach. We report here that routes to these same intermediates designed around a hydrocarbon oxidation approach are more efficient both in the total number of functional group manipulations (FGMs) and overall steps, as well as in the overall yield.