70279-22-0Relevant articles and documents
Metal Exchange Reaction of Cd(II) 5,10,15,20-Tetra(4-chlorophenyl)porphyrinate with Copper and Zinc Chlorides in DMSO
Zvezdina,Chizhova,Mamardashvili, N. Zh.
, p. 2105 - 2110 (2020)
Abstract: The metal exchange reactions of Cd(II)5,10,15,20-tetra(4-chlorophenyl)porphyrinate with CuCl2and ZnCl2 in DMSO were studied by the spectrophotometricmethod. The kinetic parameters of the metal exchange reactions were determined.A possible reaction mechanism was proposed. Zinc(II) and copper(II)5,10,15,20-tetra(4-chlorophenyl)porphyrinates were synthesized by the complexformation reactions of zinc(II) and copper(II) acetates with5,10,15,20-tetra(4-chlorophenyl)porphyrin and by metal exchange of its cadmiumcomplex with ZnCl2 and CuCl2 indimethylformamide. The resulting compounds were identified by electronicabsorption and 1H NMR spectroscopy and massspectrometry methods.