70286-37-2

Basic information

• Product Name: Benzaldehyde, 4-methoxy-, O-methyloxime, (E)-
• CAS NO: 70286-37-2
• Molecular Formula: C9H11NO2
• Molecular Weight: 165.192
• Mol File: 70286-37-2.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 4-methoxy-, O-methyloxime, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 4-methoxy-, O-methyloxime, (E)-(70286-37-2)
• EPA Substance Registry System: Benzaldehyde, 4-methoxy-, O-methyloxime, (E)-(70286-37-2)

Safety Data

• Hazardous Substances Data: 70286-37-2(Hazardous Substances Data)

Upstream product

• 593-56-6 N-methoxylamine hydrochloride 
• 123-11-5 4-methoxy-benzaldehyde 
• 105-13-5 4-Methoxybenzyl alcohol 
• 3717-21-3 p-methoxyl benzaldoxime 
• 74-88-4 methyl iodide 
• 87861-04-9 (Z)-4-methoxybenzaldehyde O-methyloxime 
• 60-29-7 diethyl ether 
• 3717-21-3 (E)-4-methoxybenzaldoxime 
• 3717-22-4 (Z)-para-methoxybenzaldehyde oxime 
• 149-73-5 trimethyl orthoformate 
• 77-78-1 dimethyl sulfate 
• 124-41-4 sodium methylate 
• 7647-01-0 hydrogenchloride 
• 2181-42-2 trimethylsulphonium iodide 

Downstream Products

• 874-90-8 4-methoxybenzonitrile 
• 6265-92-5 2-(4-methoxy-phenyl)-benzothiazole 

Relevant articles and documents

A Short Total Synthesis of Benzophenanthridine Alkaloids via a Rhodium(III)-Catalyzed C-H Ring-Opening Reaction

The biologically important naturally available benzophenanthridines were prepared efficiently in three steps with overall good yields. A new synthetic methodology involving a rhodium(III) catalyzed redox-neutral ring-opening of 7-azabenzonorbornadienes with aromatic aldoximes is developed to synthesize the target molecules. The developed C-H ring-opening reaction is highly diastereoselective and compatible with various sensitive functional group substituted aromatic aldoximes as well as substituted 7-azabenzonorbornadienes. The ring-opening products were transformed into highly sensitive 13,14-dehydrobenzo phenanthridine derivatives by HCl hydrolysis. Subsequently, 13,14-dehydrobenzophenanthridines were converted into biologically important benzophenanthridine alkaloids in the presence of DDQ. A possible reaction mechanism was proposed for the C-H ring-opening reaction and supported by the deuterium labeling studies.

One-pot synthesis of alternating peptides exploiting a new polymerization technique based on Ugi's 4CC reaction

We developed a one-pot synthetic technique for alternating peptides. Central to this technique is a new, catalyst-free polymerization based on Ugi's 4CC reaction. The treatment of imines with the ambident molecules bearing both an isocyanide and a carboxylic acid afforded alternating peptides.

Solid-phase synthesis of benzothiazoles using an alkoxyamine linker

An alkoxyamine linker was applied for the solid-phase synthesis of benzothiazoles. The substrate was anchored by aldoxime linkage and products were cleaved from the solid-support by aldoxime-imine exchange coupled with air-oxidation under the weakly acidi