70291-88-2

Basic information

• Product Name: 1H-Indole, 2,3-bis(phenylthio)-
• CAS NO: 70291-88-2
• Molecular Formula: C20H15NS2
• Molecular Weight: 333.478
• Mol File: 70291-88-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 1H-Indole, 2,3-bis(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indole, 2,3-bis(phenylthio)-(70291-88-2)
• EPA Substance Registry System: 1H-Indole, 2,3-bis(phenylthio)-(70291-88-2)

Safety Data

• Hazardous Substances Data: 70291-88-2(Hazardous Substances Data)

Upstream product

• 54491-43-9 3-phenylthioindole 
• 5813-48-9 Methanesulfenyl chloride 
• 931-59-9 benzenesulfenyl chloride 
• 200617-53-4 3,3-bis(phenylthio)-3H-indole 
• 882-33-7 diphenyldisulfane 
• 14204-24-1 N-(phenylthio)succinimide 
• 3419-91-8 N-(2-pyridyl)indole 
• 120-72-9 indole 
• 80-17-1 benzenesufonyl hydrazide 
• 873-55-2 sodium benzenesulfonate 
• 108-98-5 thiophenol 
• 136506-29-1 1-(2-(phenylsulfonyl)ethyl)-1H-indole 
• 63955-67-9 1-methyl-3-(phenylthio)-1H-indole 
• 136506-30-4 1-(2-phenylsulfonylethyl)-2,3-diphenylthioindole 

Downstream Products

• 98508-75-9 1-Benzyl-2,3-bis-phenylsulfonylindole 
• 98508-79-3 (2,3-Bis-benzenesulfonyl-indol-1-yl)-acetonitrile 
• 120517-31-9 5-chloro-2-(methylthio)-1H-indole 
• 108698-81-3 1-benzyl-2,3-bis(phenylthio)indole 
• 51072-85-6 2-phenyl-1H-indole-3-carbonitrile 
• 51072-83-4 2-methyl-1H-indole-3-carbonitrile 
• 98508-76-0 2,3-Bis-benzenesulfonyl-1-ethyl-1H-indole 
• 63955-64-6 1-methyl-2,3-bis(phenylthio)-1H-indole 

Relevant articles and documents

Cp*Co(iii)-catalyzed C2-thiolation and C2,C3-dithiolation of substituted indoles withN-(arylthio)succinimide

A general and efficient Cp*CoIII-catalyzed C2-thiolation and C2,C3-dithiolation of indole derivatives has been achieved employingN-(aryl/alkylthio)succinimide as a thiolating reagent. This external oxidant-free method utilizes only catalytic amounts of additive and tolerates various functional groups to afford various thiolated products in good yields. Control experiments revealed the importance of the Cp*CoIII-catalyst for both C2- and C3-thiolation.

Cu-catalysed direct bis-thiolation of benzoheterocycles with arylsulfonyl hydrazides

A series of bis-arylsulfenylated indoles (10), benzofurans (3), and benzothiophenes (3) and of monosulfenylated indoles (5), 12 of which are novel, were prepared in good yields via a Cu-catalysed direct sulfenylation of benzoheterocycles with arylsulfonyl hydrazides. Sulfonothioates are probably the major thiolated intermediates in this transformation.

Iodine-catalysed versatile sulfenylation of indoles with thiophenols: controllable synthesis of mono- and bis-arylthioindoles

A versatile method for the synthesis of mono- and bis-arylthioindoles via I2 catalysed direct oxidative sulfenylation of indoles with thiophenols (especially mercaptobenzoic acids) has been presented. This system features environmental friendliness, easy operation, and mild reaction conditions, and shows a broad functional group tolerance furnishing good to excellent yields.