7032-25-9

Basic information

• Product Name: N-Phenyl-2-pyridylmethanimine
• Synonyms: 2-(Phenyliminomethyl)pyridine;2-Picolylidene aniline;N-(2-Pyridinylmethylene)aniline;N-(2-Pyridinylmethylene)benzenamine;N-Phenyl-2-pyridylmethanimine;N-Phenylpyridine-2-methanimine
• CAS NO: 7032-25-9
• Molecular Formula: C₁₂H₁₀N₂
• Molecular Weight: 182.22
• Mol File: 7032-25-9.mol
• Article Data: 35

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Phenyl-2-pyridylmethanimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Phenyl-2-pyridylmethanimine(7032-25-9)
• EPA Substance Registry System: N-Phenyl-2-pyridylmethanimine(7032-25-9)

Safety Data

• Hazardous Substances Data: 7032-25-9(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 1121-60-4 pyridine-2-carbaldehyde 
• 586-98-1 2-Hydroxymethylpyridine 
• 27443-36-3 pyridine-2-carboxaldehyde dimethyl acetal 
• 4329-81-1 N-phenylpyridine-2-methylamine 
• 1227476-15-4 Azobenzene 
• 6959-47-3 2-chloromethylpyridine hydrochloride 
• 538-51-2 benzylidene phenylamine 
• 622-37-7 Phenyl azide 
• 98-95-3 nitrobenzene 
• 88785-71-1 Phenyl-[1-pyridin-2-yl-meth-(Z)-ylidene]-amine 
• 29202-13-9 N-(p-dimethylaminophenyl)pyridine-2-aldimine 

Downstream Products

• 108839-30-1 1,3-diphenyl-4-[2]pyridyl-azetidin-2-one 
• 97230-34-7 2-(3-Phenyl-4,5-dihydro-3H-[1,2,3]triazol-4-yl)-pyridine 
• 1066-40-6 Trimethylsilanol 
• 62-53-3 aniline 
• 13341-40-7 (E)-1,2-bis(2-pyridyl)ethene 
• 4329-81-1 N-phenylpyridine-2-methylamine 
• 107909-53-5 N,α-Picolinyl-N-(adamant-1-yl)-anilin 
• 107909-54-6 1,2-(Dipyrid-2-yl)-1,2-dianilinoethan 
• 79388-25-3 methyl 2,2-dimethyl-3-(phenylamino)-3-(2-pyridyl)propanoate 
• 72709-32-1 N-(1-(pyridin-2-yl)but-3-enyl)benzenamine 
• 72709-31-0 2-(1-phenylpyrrolidin-2-yl)pyridine 
• 88785-71-1 Phenyl-[1-pyridin-2-yl-meth-(Z)-ylidene]-amine 
• 110362-28-2 4-Methyl-1-phenyl-6-(2-pyridyl)-5,6-dihydropyridin-2-one 

Relevant articles and documents

N,N-Chelate nickel(II) complexes bearing Schiff base ligands as efficient hydrogenation catalysts for amine synthesis

Five N, N-chelate nickel (II) complexes bearing N-(2-pyridinylmethylene)-benzylamine ligands with different substituent groups were synthesized in good yields. The nickel complexes exhibited prominent catalytic efficiency toward amine synthesis from nitro compounds by using NaBH4 or H2 as hydrogen source through two catalytic systems. Various amines with different substituents were obtained in moderate to excellent yields. All substrates with electron-donating and electron-withdrawing properties were tolerated in the two reduction systems. Given the efficient catalytic activity, broad substance scope, and mild reduction conditions, the nickel catalysts have potential applications in industrial production.

Effect of linker and metal on photoreduction and cascade reactions of nitroaromatics by M-UiO-66 metal organic frameworks

The use of metal organic frameworks (MOFs) as photocatalysts is a promising and growing area of research. Given the diverse architectures, linkers, and metals, it is important to understand their effects on catalysis. Herein we compare six MOFs of the UiO-66 family towards photocatalytic reduction of nitro-aromatics to anilines. These MOFs differ in metal identity (Hf, Zr) and linker, and hence this systematic study provides insights to developing next generation MOFs. We found that Hf-based MOFs are superior to the more commonly studied Zr-analogues. Moreover, the linker identity also impact the photocatalysis, with pyridine-based linkers out-performing aniline based linkers and those that lack an embedded basic site. The MOFs studied have unique selectivities for the photoreduction and also allow for the one-pot synthesis of imines from aromatic aldehydes and nitro-aromatics.

Controlled Single and Double Iodofluorination of Alkynes with DIH- and HF-Based Reagents

A novel protocol for the regio- and stereoselective iodofluorination of internal and terminal alkynes using 1,3-diiodo-5,5,-dimethylhydantoin and HF-based reagents is disclosed. This approach is used to prepare a fluorinated tamoxifen derivative in two steps from commercially available starting materials. A facile method enabling controlled regioselective double iodofluorination of terminal alkynes is also presented.