70338-42-0Relevant articles and documents
Chemoselective Luche-Type Reduction of α,β-Unsaturated Ketones by Magnesium Catalysis
Jang, Yoon Kyung,Magre, Marc,Rueping, Magnus
supporting information, p. 8349 - 8352 (2019/10/16)
The chemoselective reduction of α,β-unsaturated ketones by use of an economic and readily available Mg catalyst has been developed. Excellent yields for a wide range of ketones have been achieved under mild reaction conditions, short times, and low catalyst loadings (0.2-0.5 mol %).
Free-radical-initiated coupling reaction of alcohols and alkynes: Not co but C-C bond formation
Liu, Zhong-Quan,Sun, Liang,Wang, Jian-Guo,Han, Jie,Zhao, Yan-Kai,Zhou, Bo
supporting information; scheme or table, p. 1437 - 1439 (2009/09/07)
This work demonstrates an efficient method to prepare allylic alcohols via direct C-C bond formation using electron-rich alkynes and aliphatic alcohols initiated by tert-butyl hydroperoxide.