70351-86-9

Basic information

• Product Name: 2,3,6,7,10,11-Hexakis[hexyloxy]triphenylene
• Synonyms: 2,3,6,7,10,11-Hexakis[hexyloxy]triphenylene
• CAS NO: 70351-86-9
• Molecular Formula: C₅₄H₈₄O₆
• Molecular Weight: 829.24116
• Mol File: 70351-86-9.mol
• Article Data: 29

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,3,6,7,10,11-Hexakis[hexyloxy]triphenylene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,6,7,10,11-Hexakis[hexyloxy]triphenylene(70351-86-9)
• EPA Substance Registry System: 2,3,6,7,10,11-Hexakis[hexyloxy]triphenylene(70351-86-9)

Safety Data

• Hazardous Substances Data: 70351-86-9(Hazardous Substances Data)

Usage

General Description

2,3,6,7,10,11-Hexakis[hexyloxy]triphenylene is a chemical compound that belongs to the class of organic compounds known as triphenylenes. These are polyaromatic hydrocarbons (PAHs) containing three benzene rings, each sharing one side with another ring. This particular compound is distinguished by six hexyloxy groups attached to the outer carbon atoms. While there is limited information about its specific properties or applications, similar compounds have been studied for use in organic electronics, such as organic light-emitting diodes and photovoltaics. As with all chemicals, it should be handled with care to prevent any harmful exposure or reactions.

Upstream product

• 94259-20-8 1,2-dihexyloxybenzene 
• 4956-41-6 1,2-dioctyloxybenzene 
• 155787-83-0 3,3′-di(hexyloxy)-4,4′-bis(methyloxy)biphenyl 
• 160257-82-9 4,4'-bis(hexyloxy)-3,3'-dimethoxybiphenyl 
• 244091-61-0 2,3,6,7,10,11-Hexakis-trimethylsilanyloxy-triphenylene 
• 156245-10-2 1,2-bis(hexyloxy)-4,5-diiodobenzene 
• 808-57-1 2,3,6,7,10,11-hexamethoxytriphenylene 
• 111-25-1 1-bromo-hexane 
• 4877-80-9 2,3,6,7,10,11-hexahydroxytriphenylene 
• 31189-03-4 2-(hexyloxy)phenol 
• 881209-78-5 2-[3,4-bis(hexyloxy)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 120-80-9 benzene-1,2-diol 
• 200959-51-9 4-bromo-1,2-bis(hexyloxy)benzene 
• 90-05-1 2-methoxy-phenol 

Downstream Products

• 156244-98-3 2,3,6,7,10-penta(hexyloxy)-11-hydroxytriphenylene 
• 227024-10-4 2,6,10-tri(hydroxy)-3,7,11-tris(hexyloxy)triphenylene 
• 206654-95-7 η(6)-2,3,6,7,10,11-hexahexyloxytriphenylene(1,1a,2,3,4,4a)-tricarbonyl-chromium(0) 
• 1244773-43-0 3,6,7,10,11-pentakis(hexyloxy)triphenylen-2-yl 1,1,1-trifluoromethanesulfonate 
• 1280536-76-6 2-(3,3-diethoxyprop-1-yn-1-yl)-3,6,7,10,11-pentakis(hexyloxy)triphenylene 
• 1280536-79-9 3-[3,6,7,10,11-pentakis(hexyloxy)triphenylen-2-yl]prop-2-ynal 
• 1337993-22-2 C₄₉H₇₂N₂O₅ 
• 1337993-23-3 C₅₅H₈₄N₂O₅ 
• 314051-20-2 3,6,7,10,11-pentakis(hexyloxy)triphenylene-1,2-dione 
• 1209485-08-4 2,3,6,7,10-pentakis(hexyloxy)-11-(prop-2-ynyloxy)triphenylene 
• 241474-61-3 2-((10-bromo)decyloxy)-3,6,7,10,11-pentahexyloxybenzophenanthrene 

Relevant articles and documents

Highly Oriented Fibres of Discotic Liquid Crystals

Highly aligned discotic liquid crystal fibres of hexa-alkoxytriphenylene (HET-n) and its ester derivative (HAT-n) can be drawn by a new strand technique; our synchrotron X-ray scattering study indicates the single crystal quality of these fibres.

Oxidative cyclotrimerization of unsaturated compounds with DDQ and triflic acid: An efficient synthetic route to triply-fused benzene rings

Intermolecular oxidative cyclotrimerization reactions of alkenes and aromatic compounds with DDQ and trifluoromethanesulfonic acid are described. Scholl-type oxidation reactions involving alkenes have not previously been demonstrated. Moreover, the DDQ/acid system has never been used for intermolecular oxidative cyclization reactions. This convenient, metal-free reagent system (DDQ/TfOH) is advantageous with respect to metal-based Scholl-type oxidants because it eliminates the possibility of halogenation of aromatic compounds as a competing side reaction.

A new strategy towards the synthesis of a room-temperature discotic nematic liquid crystal employing triphenylene and pentaalkynylbenzene units

A new approach is reported for the design of a room-temperature discotic nematic (ND) liquid crystal (LC) dimer consisting of a triphenylene and a pentaalkynylbenzene unit linked via flexible alkyl spacers. The formation of the ND phase is realized most likely through folding of the dimeric molecule that prevent stacking between the triphenylene units, as suggested by modelling in the mesophase derived from X-ray scattering results and high-level DFT calculations.

Triphenylene derivative and use thereof

A triphenylene derivative of general formula (I) or general formula (II) which can be used as a component of liquid crystal medium and the use thereof are provided in the present invention. This compound can be used to form a negative discotic liquid crystal composition having a suitable temperature range of liquid crystal phase and a lower clearing point, which can be used in TFT liquid crystal display as an optical compensation film (cell) material.

Self-organization of star-shaped columnar liquid crystals with a coaxial nanophase segregation revealed by a combined experimental and simulation approach

Fully consistent X-ray data and molecular dynamics simulations on new star-shaped liquid crystals yield two nanosegregated architectures with a coaxial stacking of two functional discotic units: tris(triazolyl)triazine and triphenylene. Analysis of lattice order along the principal axes reveals preferential staggered arrangement of the stacked molecules in the columnar assembly.