70401-31-9

Basic information

• Product Name: 2-Methyl-5H-dibenz[b,f]azepine
• Synonyms: 2-Methyl-5H-dibenz[b,f]azepine;2-Methyl-5H-dibenzazepine
• CAS NO: 70401-31-9
• Molecular Formula: C15H13N
• Molecular Weight: 207.27042
• Product Categories: Amines;Heterocycles;Intermediates & Fine Chemicals;Pharmaceuticals
• Mol File: 70401-31-9.mol
• Article Data: 2

Chemical Properties

• Melting Point: 159-162 °C(Solv: cyclohexane (110-82-7))
• Boiling Point: 358.6±37.0 °C(Predicted)
• Appearance: /
• Density: 1.094±0.06 g/cm3(Predicted)
• PKA: 2.21±0.20(Predicted)
• CAS DataBase Reference: 2-Methyl-5H-dibenz[b,f]azepine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methyl-5H-dibenz[b,f]azepine(70401-31-9)
• EPA Substance Registry System: 2-Methyl-5H-dibenz[b,f]azepine(70401-31-9)

Safety Data

• Hazardous Substances Data: 70401-31-9(Hazardous Substances Data)

Usage

Chemical Properties

Yellow Solid

Uses

Intermediate in the preparation of 2-Methyl Carbamazepine (M266160).

Upstream product

• 167283-32-1 N-(p-tolyl)indole 

Relevant articles and documents

Rearrangement of 1-Arylindoles to 5H-Dibenzazepines

An unusual acid-catalyzed rearrangement of 1-arylindoles 1 to 5H-dibenzazepines 2 has been discovered.It can be used for the preparation of 2.The influence of the nature and the position of the substituents in the initial molecule 1 on the rearrangement is discussed.A possible mechanism of the reaction is suggested.A convenient method for preparation of 1-arylindoles 1c-k by means of arylation of 1-unsubstituted indoles with aryl halides by the Ullmann reaction is described.