7045-71-8Relevant articles and documents
Selective hydroisomerization of n-dodecane over platinum supported on zeolites
Yun, Soyoung,Lee, Eunok,Park, Young-Kwon,Jeong, Soon-Yong,Han, Jeongsik,Jeong, Byunghun,Jeon, Jong-Ki
, p. 1215 - 1223 (2011)
In this study, in order to develop catalysts for the selective isomerization of higher paraffin, the hydroisomerization reaction of n-dodecane was performed as a model reaction. Pt/ZSM-48, Pt/HZSM-5, Pt/HY, and Pt/SAPO-11 were examined for the selective hydroisomerization of n-dodecane. The catalysts were characterized via X-ray powder diffraction, N2 adsorption, and the temperature-programmed desorption of ammonia. Among the catalysts studied, the Pt/HZSM-48 catalyst exhibited the best isomerization selectivity in the hydroisomerization reaction of n-dodecane, which is attributed to the moderate acid sites and medium-sized pores present in the HZSM-48. The highest iso-dodecane yield was obtained at a reaction temperature of 280 °C in the Pt/HZSM-48 catalyst. The optimal selectivity of the n-dodecane hydroisomerization over the Pt/SAPO-11 catalyst was obtained at approximately 300 °C, which was slightly higher than that of the Pt/HZSM-48 catalyst.
AIR-STABLE NI(0)-OLEFIN COMPLEXES AND THEIR USE AS CATALYSTS OR PRECATALYSTS
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Page/Page column 20-21, (2021/02/05)
The present invention relates to air stable, binary Ni(0)-olefin complexes and their use in organic synthesis.
Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents
Iwasaki, Takanori,Yamashita, Koji,Kuniyasu, Hitoshi,Kambe, Nobuaki
supporting information, p. 3691 - 3694 (2017/07/26)
The cross-coupling reaction of unactivated alkyl fluorides with alkyl Grignard reagents by a CoCl2/LiI/1,3-pentadiene catalytic system is described. The present reaction smoothly cleaved C-F bonds under mild conditions and achieved alkyl-alkyl cross-coupling even when sterically hindered tertiary alkyl Grignard reagents were employed. Since alkyl fluorides are inert toward many reagents and catalytic intermediates, the use of the present reaction enables a new multistep synthetic route to construct carbon frameworks by combining conventional transformations.
Synthesis, characterization and isomerization performance of micro/mesoporous materials based on H-ZSM-22 zeolite
Liu, Suyao,Ren, Jie,Zhang, Huaike,Lv, Enjing,Yang, Yong,Li, Yong-Wang
, p. 11 - 23 (2016/01/20)
Micro/mesoporous materials with different mesoporosities were prepared through recrystallization of H-ZSM-22 zeolite in alkaline solution with cetyltrimethylammonium bromide template (CTAB). The structure, morphology, pore properties, acidity and isomerization performance of the catalysts by using the resulting materials were characterized and assessed. The dissolution and recrystallization procedure introduced the well-developed mesoporous structure of MCM-41 type with the meso-scale channels of about 3 nm in size on the outer surfaces of the microporous H-ZSM-22 zeolites, forming the micro/mesoporous materials, which possessed increased weak B acid sites at the pore mouths and a reduced amount of total acid sites. It is shown that the presence of well-developed mesopores could remarkably improve the selectivity to multi-branched products and suppress the side cracking reactions in n-dodecane isomerization. The micro/mesoporous Pt/ZSM-22/MCM-41 bifunctional catalyst with suitable recrystallization degree exhibits high isomerization selectivity under high conversion in long-chain n-alkane isomerization compared to the original microporous Pt/H-ZSM-22 catalyst.