70473-50-6Relevant articles and documents
Selective 1,5-Diene Synthesis. A Radical Approach
Yanagisawa, Akira,Noritake, Yoshiyuki,Yamamoto, Hisashi
, p. 1899 - 1902 (1988)
A new synthetic route to 1,5-dienes is described.Irradiation of a mixture of allyl bromides and allyl sulfides in the presence of hexamethylditin gives the cross-coupled products selectively.
New Entry to γ,δ-Unsaturated Seven-membered Lactones
Kido, Fusao,Kazi, Abul B.,Yoshikoshi, Akira
, p. 613 - 616 (2007/10/02)
The sigmatropic rearrangement of cyclic allyl-sulfonium ylides, generated from the diazo malonates of 2-phenylthio-3-butenol derivatives with catalytic rhodium acetate, afforded γ,δ-unsaturated seven-membered lactones in moderate to good yields.