7055-03-0

Basic information

• Product Name: 2-METHYLBENZANILIDE
• Synonyms: O-METHYL BENZANILIDE;O-TOLUANILIDE;2-methylbenzoanilide;2-methylbenzoicacidanilide;2-methyl-n-phenyl-benzamid;2-methyl-n-phenylbenzamide;bas305;bas-3050
• CAS NO: 7055-03-0
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.26
• EINECS: 230-334-4
• Product Categories: Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
• Mol File: 7055-03-0.mol
• Article Data: 75

Chemical Properties

• Melting Point: 125°C
• Boiling Point: 350.95°C (rough estimate)
• Flash Point: 162.2oC
• Appearance: /
• Density: 1.0694 (rough estimate)
• Vapor Pressure: 0.00483mmHg at 25°C
• Refractive Index: 1.5780 (estimate)
• PKA: 13.53±0.70(Predicted)
• CAS DataBase Reference: 2-METHYLBENZANILIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYLBENZANILIDE(7055-03-0)
• EPA Substance Registry System: 2-METHYLBENZANILIDE(7055-03-0)

Safety Data

• Hazardous Substances Data: 7055-03-0(Hazardous Substances Data)

Usage

Uses

o-Toluanilide is a systemic fungicide used in pesticide formulations.

InChI:InChI=1/C14H13NO/c1-11-7-5-6-10-13(11)14(16)15-12-8-3-2-4-9-12/h2-10H,1H3,(H,15,16)

Upstream product

• 529-19-1 2-Methylbenzonitrile 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 131-58-8 2-Methylbenzophenone 
• 85515-91-9 (Z)-phenyl(o-tolyl)methanone oxime 
• 932-31-0 ortho-tolylmagnesium bromide 
• 103-71-9 phenyl isocyanate 
• 118-90-1 ortho-methylbenzoic acid 
• 62-53-3 aniline 
• 694-59-7 pyridine N-oxide 
• 51619-51-3 2-methyl-N-phenyl-benzimidoyl chloride 
• 933-88-0 ortho-toluoyl chloride 
• 10026-13-8 phosphorus pentachloride 
• 85515-91-9 (E)-phenyl(o-tolyl)methanone oxime 
• 615-37-2 ortho-methylphenyl iodide 

Downstream Products

• 51619-51-3 2-methyl-N-phenyl-benzimidoyl chloride 
• 65492-63-9 N-(4-chlorophenyl)-2-methylbenzamide 
• 22978-54-7 2',4'-Dichlor-2-methylbenzanilid 
• 529-20-4 2-methylphenyl aldehyde 
• 65786-51-8 (4-(dimethylamino)phenyl)(o-tolyl)methanone 
• 5892-77-3 (2-Methyl-benzoyl)-phenyl-carbamic acid isopropyl ester 
• 110966-95-5 N-[1-Phenylamino-1-o-tolyl-meth-(E)-ylidene]-benzenesulfonamide 
• 110966-97-7 4-Chloro-N-[1-phenylamino-1-o-tolyl-meth-(E)-ylidene]-benzenesulfonamide 
• 95087-91-5 o-Toluanilide-4'-sulfonyl chloride 
• 95087-93-7 o-Toluanilide-4',5-bis sulfonyl chloride 
• 110966-96-6 4-Methyl-N-[1-phenylamino-1-o-tolyl-meth-(E)-ylidene]-benzenesulfonamide 
• 82071-21-4 n,3-diphenylisoquinolin-1-amine 
• 493-77-6 2,4,6-triphenyl-1,3,5-triazine 
• 119298-23-6 2-(1-butenyl)benzanilide 

Relevant articles and documents

Metal-free transamidation of benzoylpyrrolidin-2-one and amines under aqueous conditions

N-Acyl lactam amides, such as benzoylpyrrolidin-2-one, benzoylpiperidin-2-one, and benzoylazepan-2-one reacted with amines in the presence of DTBP and TBAI to afford the transamidated products in good yields. The reactions were conducted under aqueous conditions and good functional group tolerance was achieved. Both aliphatic and aromatic primary amines displayed good activity under metal-free conditions. A radical reaction pathway is proposed.

Visible-Light Carbon Nitride-Catalyzed Aerobic Cyclization of Thiobenzanilides under Ambient Air Conditions

A metal-free heterogeneous photocatalysis has been developed for the synthesis of benzothiazoles via intramolecular C-H functionalization/C-S bond formation of thiobenzanilides by inexpensive graphitic carbon nitride (g-C3N4) under visible-light irradiation. This reaction provides access to a broad range of 2-substituted benzothiazoles in high yields under an air atmosphere at room temperature without addition of a strong base or organic oxidizing reagents. In addition, the catalyst was found to be stable and reusable after five reaction cycles.

Cobalt-Catalyzed Deoxygenative Hydroboration of Nitro Compounds and Applications to One-Pot Synthesis of Aldimines and Amides

The commercially available and bench-stable Co(acac)2 ligated with bis[(2-diphenylphosphino)phenyl] ether (dpephos) was employed for selective room temperature hydroboration of nitro compounds with HBPin (TOF up to 4615 h?1), tolerating halide, hydroxy, amino, ether, ester, lactone, amide and heteroaromatic functionalities. These reactions offered a direct access to a variety of N-borylamines RN(H)BPin, which were in situ treated with aldehydes and carboxylic acids to produce a series of aldimines and secondary carboxamides without the need for dehydrating and/or coupling reagents. Combination of these transformations in a sequential one-pot manner allowed for direct and selective synthesis of aldimines and secondary carboxamides from readily available and inexpensive nitro compounds.